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117 articles for “kinetics”
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Novel method for determination of kinetic constants from dynamics in a batch reactor with constant heat input rate
Abstract: In this article a novel method of obtaining reaction kinetic constants is described. It consists of measuring both concentration and temperature dynamics in a batch reactor supplied with a constant heat input rate. A system of esterification reaction between acetic acid and methanol in the presence of a cationic resin catalyst is studied. This reversible reaction’s rate is modeled by molecular order and as pseudo homogeneous assumption. By just one …
Published in International journal of Thermodynamics and Chemical Kinetics · Vol. 5, Issue 1, 2019 · pp. 19–23 Read article
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Evaluation of Corrosion kinetics of zirconium dioxide dispersion strengthened Aluminium metal matrix composites
Abstract: The corrosion kinetics of Aluminum 7068-Zirconium dioxide composites is a major aspect for assessing the capability of utilizing the materials for aviation segments. Aluminum 7068 matrix is a particular class of composite which is known for its high strength characteristics even in critical situations and is utilized as a part of aerospace, automobile and ordinance applications. However the investigations on impact of reinforcements, for instance zirconium dioxide on corrosion conduct …
Published in International Journal of Metallurgy and Alloys · Vol. 4, Issue 1, 2018 · pp. 9–23 Read article
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Kinetic Model for Production of Carbon(iv)oxide (CO2) from Brewers Spent Grain Using Anaerobic Digester
Abstract: In this research paper, investigation studies were carried out to determine which model best predicts the amount of using the linear, power, growth rate decay, and non-elementary rate models, the kinetics of the biogas produced under the impact of biodegradation were explored. Carbon(iv)oxide was produced as a fraction of the biogas acquired from the experimental conditions. Either of the linear, power, growth rate decay, and non-elementary rate models can be …
Published in International Journal of Energetic Materials · Vol. 10, Issue 1, 2024 · pp. 17–31 Read article
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Recovery of Succinic acid by Reactive Extraction using Tri-n-octylamine in 1-Decanol: Equilibrium Optimization using Response Surface Method and Kinetic studies
Abstract: Reactive extraction is a promising technique for the recovery of organic acids from aqueous streams. Succinic acid, is a white, odorless solid dicarboxylic acid, and is a precursor for some specialized polyesters. Present paper presents an optimization study of reactive extraction of succinic acid equilibrium studies from aqueous solutions using Tri-n-octylamine in 1-Decanol using response surface methodology including reaction kinetics in a stirred cell. Extraction efficiency (Y), a response function …
Published in International Journal of Chemical Separation Technology · Vol. 2, Issue 2, 2016 · pp. 1–14 Read article
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Equilibrium and kinetic studies on reactive extraction of lactic acid
Abstract: Abstract: Lactic acid has became a growing requirement in various fields so reactive extraction has been employed to recover by using tri pentyl amine and tertiary butyl amine in different diluents (1-octanol, chloroform and dimethylene chloride). Physical and chemical equilibrium isotherms, KD, loading ratio (Z) were measured through equilibrium studies for (1:1) and (2:1) acid amine complex formation at room temperature. By conducting kinetic studies in batch type reactive system …
Published in International Journal of Chemical Separation Technology · Vol. 4, Issue 2, 2018 · pp. 35–46 Read article
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Mechanical Studies and Thermal Kinetics of Isoniazid Crystals
Abstract: Single crystals of isoniazid were crystallized by slow solvent evaporation method. The crystal structure was confirmed using single crystal X-ray diffraction analysis. Micro hardness was estimated and work hardening coefficient and Newtonian resistance pressure of the crystal were determined. Kinetic analysis of the thermogravimetric data was carried out by using Coats-Redfern relation. Activation energy, frequency factor and order of reaction were also calculated. Arrhenius equation for isoniazid is k=0.43×105e–79103/RT mol–1s–1. …
Published in International Journal of Chemical Synthesis and Chemical Reactions · Vol. 1, Issue 1, 2015 Read article
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Thermal Decomposition Kinetics of Mefenamic Acid Crystals
Abstract: Single crystals of mefenamic acid were crystallized by gel growth method for the first time in literature. Crystal structure was confirmed using single crystal X-ray diffraction analysis. Kinetic analysis was made from the isothermal thermogravimetric analysis/differential thermal analysis (TGA/DTA) data using Coats–Redfern (CR) relation. Thermodynamic parameters were also determined. Arrhenius equation for mefenamic acid is k = 0.28 × 109 e–116551/RT mol–1s–1. Keywords: kinetic analysis, mefenamic acid, thermal analysis
Published in International journal of Thermodynamics and Chemical Kinetics · Vol. 2, Issue 1, 2016 · pp. 21–24 Read article
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Kinetic and Thermodynamic Studies of Adsorption of Pb (II) by Using Ferrous Sulphide as an Adsorbent
Abstract: Poisoning of lead is causing a serious threat to the environment. In the present study the adsorption behaviour of lead was studied in detail by ferrous sulphide in granular form. Ferrous sulphide has the magnetic properties and makes it a better candidate for lead removal. Batch adsorption experiments were carried out by varying different process parameters such as contact time, adsorbent dose, pH, and temperature. Lead adsorption by ferrous sulphide …
Published in International Journal of Chemical Engineering and Processing · Vol. 2, Issue 2, 2016 · pp. 33–41 Read article
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Kinetics of Oxidation of L-Proline by Hexacyanoferrate (III) Ion in Presence of Os (VIII)
Abstract: Amino acids are building block of proteins and maintaining a vital role in growth of human beings as well as animals. Amino acids may form metal complexes and other complexes in animal and human body. Therefore, the study of oxidation of amino acids as well as their complexes is interesting area for academicians and physicians. Amino acids are the compounds of two functional groups -NH2 and –COOH. Hence depending on …
Published in International Journal of Chemical Engineering and Processing · Vol. 7, Issue 1, 2021 · pp. 12–24 Read article
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Investigation into the Kinetics of Biodegradation of Crude Oil Hydrocarbon in Different Soil Types Using Aloe Vera
Abstract: A pilot study was conducted on three different soil type contaminated with crude oil bio-simulated with Aloe vera juice to examine the effect of the stimulant on the rate of degradation of the crude oil by the indigenous microbes. Soil contaminated with crude is deficient of the essential nutrients which are needed to boast the activities of the microbes which feed on the crude. These nutrients are found in Aloe …
Published in International Journal of Chemical Synthesis and Chemical Reactions · Vol. 4, Issue 2, 2018 · pp. 10–21 Read article
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Kinetics and Mechanism of Ruthenium(III) Catalysed Oxidation of L-Arginine by Periodate in Alkaline Medium
Abstract: The kinetics of the ruthenium(III) catalysed oxidation of L-arginine by periodate was studied spectrophotometrically in alkaline medium at 280 nm and at a temperature 35 ± 0.1°C. It was found that the reaction is first order with respect to [catalyst] and [periodate]. The reaction showed fractional order dependence on [substrate] and [alkali]. The oxidation product of the reaction was found to be aldehyde. The anionic species of arginine (Arg) is …
Published in International journal of Thermodynamics and Chemical Kinetics · Vol. 2, Issue 1, 2016 · pp. 12–20 Read article
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Kinetic and Mechanistic Study of Oxidation of Benzydamine Hydrochloride by Permanganate (VII) in Acidic Medium
Abstract: The kinetics and mechanism of Permanganate (Mn (VII)) oxidation of Benzydamine hydrochloride (B.HCl) in acidic medium has been studied at 26 ± 0.1°C. The reaction shows first order dependence in [Mn (VII)], less than unit order in [B.HCl] and fractional order dependence in [H2SO4]. Variation of ionic strength by the addition of KCl has no significant effect on the rate. The stoichiometry of the reaction is found to be 1:4 …
Published in International journal of Thermodynamics and Chemical Kinetics · Vol. 2, Issue 2, 2016 · pp. 20–28 Read article
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Kinetics of Nucleation and Growth of Metal Nanoparticles – A Mini Review
Abstract: The prediction of nucleation and growth model for metal nanoparticles is very much important in the field of catalysis and fuel cell technology. In this mini review, discuss the initial stages of nucleation and growth model for 2D and 3D instantaneous and progressive nucleation kinetics explained. Keywords: instantaneous, nucleation, nucleation rate, progressive
Published in International journal of Thermodynamics and Chemical Kinetics · Vol. 3, Issue 1, 2017 · pp. 15–18 Read article
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Kinetics of oxidation of mixture of oxalic acid and glutaric acid by chromic acid in presence of sodium chloride and potassium chloride
Abstract: Effect of Sodium Chloride and Potassium chloride on the co-oxidation of oxalic Acid and glutaric Acid by Chromic Acid has been studied. The products are carbonyl di carboxylic Acid and Carbon dioxide. The rate of oxidation decreases with the increase in the concentration of Sodium Chloride and Potassium Chloride. It is found that Potassium Chloride is the most effective in retarding the reaction rate comparison to Sodium Chloride. The order …
Published in International journal of Thermodynamics and Chemical Kinetics · Vol. 5, Issue 2, 2019 · pp. 4–8 Read article
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Correlation for Photocatalytic Degradation Kinetics of Carboxylic Acids by Electrochemically Synthesized Cd/ZnO Nanoparticles and Study of Antibacterial Behaviour
Abstract: Cd/ZnO nanoparticle has been successfully synthesized by electrochemical method which is simple and inexpensive method. The synthesized Cd/ZnO nanoparticle was used has a catalyst for the photodegradation of Oxalic acid, Chloroacetic acid and Formic acid under various experimental conditions by volumetric method. The Cd/ZnO nanoparticles were characterized by various techniques such as SEM-EDAX, UV-Visible spectroscopy, FTIR-IR spectrum and X-ray diffraction studies. The study of UV-Visible spectroscopy revealed that the Cd/ZnO …
Published in International Journal of Nanomaterials and Nanostructures · Vol. 6, Issue 2, 2020 · pp. 1–16 Read article
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Kinetic Study of Polyester Derived from Glycolyzed PET Waste With Varied Composition
Abstract: In this investigation, the production of secondary value-added products, such as saturated polyester, derived from the glycolysis of poly(ethyleneterephthalate) (PET) is examined as an effective way for PET recycling. The glycolyzed PET (GPET) obtained was reacted with mixture of phthalic anhydride and glycol with varied composition and their reaction kinetic were studied. During polyesterification it was observed that degree of polymerization (DPn) and extent of reaction (p) is increased, while …
Published in International Journal of Polymer Science and Engineering · Vol. 1, Issue 1-2, 2015 Read article
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Study of PLA and its Synthesis Kinetics
Abstract: In this project we studied about Polylactic Acid and its production kinetics. The most often found optically active hydroxycarboxylic acid is lactic acid (LA, also known as 2-hydroxypropionic acid). In the form of L-and D-Lactic Acid, this chiral molecule may be found. The building blocks of polylactide are carboxylic acid monomers produced by fermentation of sugars from renewable sources, such as sugar cane, beet root, or corn starch. These sugars …
Published in International Journal of Polymer Science and Engineering · Vol. 8, Issue 1, 2022 · pp. 16–27 Read article
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Bio-stimulation with Fresh Avocado Seed for Crude Oil Remediation: Experimental and Bio-kinetic Modelling
Abstract: The remediation of crude oil-contaminated soils requires sustainable and cost-effective solutions. This study investigates the performance of fresh avocado seed (Persea americana) as a biostimulant for the remediation of Bonny Light crude oil-contaminated soil from the Kalarugbana community, Niger Delta. A 56-day laboratory-scale experiment was conducted using bioreactors containing 1 kg of soil contaminated with 100 ml of crude oil and treated with different volumes of fresh avocado seed slurry …
Published in International Journal of Environmental Chemistry · Vol. 11, Issue 2, 2025 · pp. 68–76 Read article
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Characterization and Kinetic Study of Sugarcane Bagasse for the Production of Bio-oil Over Monodispersed Fe2 O3 and ZSM-5 Composite
Abstract: The shortage and price scramble of fossil fuels accompanied by vast CO2 emissions have triggered a worldwide search for alternative and sustainable resources. Wind, solar, geothermal, biomass, and water are the most commonly used alternative energy sources. The biomass residues are typically at low cost and readily availabile, and has been used as feedstocks for synthesis of renewable energy. To produced the bio-fuels from biomass residues, several reaction pathways categorized …
Published in International Journal of Renewable Energy and its Commercialization · Vol. 9, Issue 2, 2023 · pp. 1–13 Read article
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Simulation of Heat Generated on Crude Oil Degradation upon the Effect of Temperature in Bacteria Growth Kinetics in a Bioreactor
Abstract: Model was established to simulate the heat generated by bacteria with the interaction of substrate (crude oil) degradation in a bioreactor upon the influence of temperature. The model was predicted by simulating the characteristics of bacteria interaction with substrate at temperature of 15oC, 30oC, 45oC, 60oC, 75oC, 90oC, 105oC and 120oC and heat generated is within the range of -1.0 to 7.1kcal/hr for bacteria in fresh water medium whereas for …
Published in International journal of Thermodynamics and Chemical Kinetics · Vol. 8, Issue 2, 2022 · pp. 39–54 Read article