All articles
120 articles
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Aerogel from Ceramic Composite
Abstract: This article is written from conferred articulated forms of aerogel. Sol-gel is a usual method toprepare aerogel. Compromise of inherent fragile mater under extensive moisture absorption tendencyof silica network has mitigated after inclusive of polyhedral oligomeric silsesquioxane (POSS)molecule. Long term applicability of silica aerogel has cited to confer superhydrophobic and flexibleconfigure based on synthesis by the catalysed sol-gel process; in accord of usual two-step method ofacid activation followed by basic …
Published in International Journal of Chemical Synthesis and Chemical Reactions · Vol. 7, Issue 1, 2021 · pp. 1–12 Read article
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Survey on Semicarbazide and Thiosemicarbazide Derivatives
Abstract: This review insurances around semicarbazide and thiosemicarbazide with derivatives throughpresentation of their preparation methods, reactions like cyclization processes. Thiosemicarbazonesand semicarbazones are an important class of ligands for the synthesis of transition metal complexeswith applications in medicine and electrochemistry, also in organic chemistry fields., Tumor is amalignant in addition invasive development or cancer, particularly of epithelium derivation, whichinclines to recur after erasure also may metastasize to other places. It befalls due …
Published in International Journal of Chemical Synthesis and Chemical Reactions · Vol. 7, Issue 1, 2021 · pp. 51–57 Read article
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Short Report on Capillary Motion of Dyed Ethylene Glycol for Application towards the Gas Flow in Microfluidics
Abstract: In this experimental report, a couple of SU-8 based glass microfluidic devices are fabricated bymaskless lithography and indirect bonding technique. Each device is tested by the prepared dyedethylene glycol as working liquid. The microfluidic-leakage is recorded in the surface-drivencapillary motion of dyed ethylene glycol due to improper indirect bonding technique. The leakagefreesurface-driven capillary motion of dyed ethylene glycol is recorded due to proper indirectbonding technique. This experimental work is performed …
Published in International Journal of Chemical Synthesis and Chemical Reactions · Vol. 7, Issue 1, 2021 · pp. 13–16 Read article
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Review Paper on Mannich Bases for Heterocyclic Compound Synthesis
Abstract: Mannich bases are the Lewis bases which are β-amino carbonyl compounds synthesized as the endproducts of well known condensation reaction known as Mannich reaction. These are theaminoalkylation reactions involving the formation of carbon-carbon, carbon-Nitrogen, carbonsulphurbonds. Mannich bases of 2-furylmethylketone, catechol, 4-chlorophenol, derivative ofberberine, lawsone, anisaldehyde, benzaldehyde show diversity of biological activities. Mannichreaction is a carbon-carbon bond forming nucleophilic addition reaction and is a key step in synthesisof a widespread variety …
Published in International Journal of Chemical Synthesis and Chemical Reactions · Vol. 7, Issue 1, 2021 · pp. 39–50 Read article
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Magnification of the Mechanism of Enzyme Catalyzed Reaction through Geometric Model
Abstract: The geometric model is dealing with correlation between the “five events for enzyme catalyzed reaction” and “triple point event serving groups on the circle” in triangle obtained for thegraphical presentation of the double reciprocal (1÷S versus 1÷V) for magnification of the mechanism of enzyme catalyzed reaction. This model is based on the nine point circle in triangle of the double reciprocal plot. The five significant points resulted for the circle …
Published in International Journal of Chemical Synthesis and Chemical Reactions · Vol. 6, Issue 2, 2020 · pp. 1–25 Read article
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Synthesis, characterization of Schiff base and its pH metrically studies of transition metal complexes of N'-(3, 4-dihydroxybenzylidene) isonicotinohydrazide.
Abstract: Schiff reaction is one of the versatile reaction widely used in organic synthesis focused on the discovery & development of isoniazide Schiff base derivative N’(3,4-Dihydroxy benzylidene isonicotinohydrazide) have been reported in presence of 0.01g molecular iodine catalyst stirring give fast product & good yield. The synthesized compound is characterized by FTIR & H-NMR analysis. For the development of coordination chemistry Schiff base & metal ion having played most important role, …
Published in International Journal of Chemical Synthesis and Chemical Reactions · Vol. 6, Issue 2, 2020 · pp. 39–47 Read article
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The Improvement of Polyvinyl Chloride Synthesis Using Different Approaches
Abstract: Polyvinyl chloride (PVC) is produced by the polymerization of the vinyl chloride monomer either by direct chlorination of olefins or by addition of hydrogen chloride to acetylene. The polymerization conditions are: heat, peroxides or oxidizing agents with basic structure as -CH2CHCl.CHCl-CH2.CHCl-. Polyvinyl chloride is a thermoplastic and its plasticity can be increased by incorporating ‘plasticizers’ of relatively low molecular weight organic materials during molding or extrusion. PVC has high hardness …
Published in International Journal of Chemical Synthesis and Chemical Reactions · Vol. 6, Issue 2, 2020 · pp. 48–52 Read article
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Overview on the Synthesis and Characteristics of Polystyrene
Abstract: Polystyrene, a synthetic aromatic polymer, is one of the most wide spread polymers in the world. The monomer is styrene (vinylbenzene)- a petroleum based liquid hydrocarbon. Polystyrene can be solid or foamed. It was first discovered by a German apothecary Edmon Simon as far back as in 1839 from the resin of Turkish sweet gum trees. Polystyrene is formed by a polymerization method known as chain growth. Physically, it is …
Published in International Journal of Chemical Synthesis and Chemical Reactions · Vol. 6, Issue 2, 2020 · pp. 26–30 Read article
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SYNTHESIS AND IR-SPECTROSCOPIC STUDY OF MIXED LIGAND COMPLEX COMPOUNDS OF COPPER (II) FORMAT WITH SOME AMIDES
Abstract: Complex compounds of metals with amides, having biological activity are widely used in agriculture. Complex compounds of copper with organic ligands are physiologically active, participating in the vital processes of living organisms; the formiats have bactericidal and fungicidal properties. For the first time, mixed ligand complex compounds of copper (II) formate with formamide, thiocarbamide, acetamide and carbamide in an aqueous solution were synthesized. Using the methods of IR spectroscopy and …
Published in International Journal of Chemical Synthesis and Chemical Reactions · Vol. 6, Issue 2, 2020 · pp. 31–38 Read article
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Review on Chalcone (Preparation ,Reactions, Medical and Bio Applications)
Abstract: This survey provides information on( methods of synthesis , reactions , applications in the medical and biological activities , its uses and its source as (whether natural or synthetic) . Chalcones are chemical compounds or natural molecules have a broad spectrum of bio- activities, which are of great interest in many fields. The chemistry of chalcones appeared information about its preparation methods as a starting material in many reactions like …
Published in International Journal of Chemical Synthesis and Chemical Reactions · Vol. 5, Issue 1, 2019 · pp. 16–27 Read article
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Fundamentals of Mass Transfer Operations
Abstract: Mass transfer operation is one of the most important subjects in chemical engineering. It contains concepts of diffusion, mass transfer coefficient and interface mass transfer. Also important unit operations such as distillation, absorption, extraction, crystallization, drying, humidification and dehumidification are covered in mass transfer operation. We come across these unit operation in our domestic applications and day to day life. These unit operations can be intensified to improve the cost …
Published in International Journal of Chemical Synthesis and Chemical Reactions · Vol. 6, Issue 1, 2020 · pp. 15–18 Read article
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REVIEW ON PREPARATION METHODS & APPLICATION FIELDS OF OXADIAZOLE
Abstract: This review displays oxadiazole (five-ring) that is of great importance in the fields of pharmacy, medicine, and field of coordinated chemistry and as reagents to estimate the small quantities of trace elements and minerals. Oxadiazole is a primary role and as a basic substance for many pharmacokinetic compounds such as antimalarial drugs, anti- bacterial, and cancerous tumors. This survey described several approach for preparation methods of oxadizole with their applications …
Published in International Journal of Chemical Synthesis and Chemical Reactions · Vol. 6, Issue 1, 2020 · pp. 49–60 Read article
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REVIEW ON PREPARATION & APPLICATIONS OF THIADIAZOLE DERIVATIVES
Abstract: This review has touched on thiadiazole derivatives as it is a basis for the synthesis of many drugs, industrial compounds, chemical dyes, pharmaceuticals and life substances, and as a link to many cyclic reactions and is produced in vitro methods for the hydrolysis of the amine-thiol compounds such as thiosemicarbazide and hydrazo-thion, among others. On the different methods of preparation for thiadiazole derivatives, its reactions and its various biological applications., …
Published in International Journal of Chemical Synthesis and Chemical Reactions · Vol. 6, Issue 1, 2020 · pp. 19–30 Read article
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Examination of White Specie Onion for Production of Oil: Integration for Pharmaceutical Production
Abstract: Research work was carried out to examiner the characteristics of oil produced from white specie of onion obtained in Nigeria. The following functional parameters were examined with therefractive index of 1.34926, density of 1.1036g/cm3, viscosity of 2.45cst, iodine value of 28.1083%, saponification value of 10.94%, free fatty acid (FFA) of 11.264%, peroxide value of 45% and acid value of 2.104%. The result obtained reveals the significance of white onion specie …
Published in International Journal of Chemical Synthesis and Chemical Reactions · Vol. 6, Issue 1, 2020 · pp. 1–14 Read article
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Synthesis of Different types of Heterocycles are used by Claisen rearrangement reaction
Abstract: The Claisen rearrangement is a powerful tool for carbon-carbon bond-forming reaction which was discovered by Rainer Ludwig Claisen. The discovery of the Claisen rearrangement nearly a century ago accessible a potentially useful synthetic tool to the organic chemist. Utility of this rearrangement over the decades has been realized and the reaction has drawn the consideration of numerous research groups, which has been showed in the number of publication on the …
Published in International Journal of Chemical Synthesis and Chemical Reactions · Vol. 6, Issue 1, 2020 · pp. 44–48 Read article
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Green Synthesis of Nickel(II) and Zinc(II) Complexes of Bis(Imine) Schiff base Derived from o-vanilline and m-phenylenediamine.
Abstract: The synthesis of Schiff base ligand derived from aromatic aldehyde (o-vanillin) and m-phenylenediamine via liquid-assisted mechanochemical synthesis (LAG) in the presence of small amount of dimethylformamide were reported. The Schiff base complexes of Ni(II) and Zn(II) were also synthesized mechanochemically and characterized using infra-red spectroscopy, thermogrametric analysis, energy dispersive x-ray analysis, powder x-ray diffraction, UV-Visible analysis, conductivity measurement, magnetic susceptibility measurement and CHN, micro-analysis. Infrared spectral study indicated a strong …
Published in International Journal of Chemical Synthesis and Chemical Reactions · Vol. 6, Issue 1, 2020 · pp. 31–43 Read article
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Investigation into the Kinetics of Biodegradation of Crude Oil Hydrocarbon in Different Soil Types Using Aloe Vera
Abstract: A pilot study was conducted on three different soil type contaminated with crude oil bio-simulated with Aloe vera juice to examine the effect of the stimulant on the rate of degradation of the crude oil by the indigenous microbes. Soil contaminated with crude is deficient of the essential nutrients which are needed to boast the activities of the microbes which feed on the crude. These nutrients are found in Aloe …
Published in International Journal of Chemical Synthesis and Chemical Reactions · Vol. 4, Issue 2, 2018 · pp. 10–21 Read article
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Synthesis and Characterization of Polyurethane in Powder Form
Abstract: Polyurethanes (PUs) are defined as a class of versatile materials with great potential for use in different applications, especially based on their structure-property relationships. Their specific mechanical, physical, biological, and chemical properties are attracting significant research to tailor made PUs for various applications. Enhancement of the properties and performance of PU-based materials are achieved through altering the production process or the raw materials used in their fabrication or via the …
Published in International Journal of Chemical Synthesis and Chemical Reactions · Vol. 4, Issue 2, 2018 · pp. 22–27 Read article
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The new methods of degassing fuel liquid in the tank of rocket engine and liquids in the life-support system of automatic spacecraft using the controlled vibration or the specially created temperature gradient in the liquid
Abstract: The paper presents the developed methods of degassing of fuel liquid in the fuel tank of rocket engine and liquids in the life-support system of automatic spacecraft using the controlled vibration or the specially created temperature gradient in the liquid that are simple on their of construction, economically highly effective and productive, mobile, and can be used in any part of the systems of power supply and life-support of automatic …
Published in International Journal of Chemical Synthesis and Chemical Reactions · Vol. 4, Issue 2, 2018 · pp. 28–43 Read article
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Synthetic Studies on Fused Benzodiazepines: A Class of Medicinally Privileged Heterocycles
Abstract: 1,4-Benzodiazepine is an important nitrogen heterocyclic scaffold because of its presence in various natural products, drugs and biologically active molecules. Henceforth, it is also known as privileged heterocycle in the field of medicinal to synthetic organic chemistry. Reactions towards the synthesis of five- and six- membered heterocycles are very easy and facile. On the other hand, synthesis of medium ring heterocycles is more difficult because of the thermodynamic limitations. Thus …
Published in International Journal of Chemical Synthesis and Chemical Reactions · Vol. 4, Issue 2, 2018 · pp. 44–59 Read article