Search
15 articles for “Schiff Base”
-
Green Synthesis of Nickel(II) and Zinc(II) Complexes of Bis(Imine) Schiff base Derived from o-vanilline and m-phenylenediamine.
Abstract: The synthesis of Schiff base ligand derived from aromatic aldehyde (o-vanillin) and m-phenylenediamine via liquid-assisted mechanochemical synthesis (LAG) in the presence of small amount of dimethylformamide were reported. The Schiff base complexes of Ni(II) and Zn(II) were also synthesized mechanochemically and characterized using infra-red spectroscopy, thermogrametric analysis, energy dispersive x-ray analysis, powder x-ray diffraction, UV-Visible analysis, conductivity measurement, magnetic susceptibility measurement and CHN, micro-analysis. Infrared spectral study indicated a strong …
Published in International Journal of Chemical Synthesis and Chemical Reactions · Vol. 6, Issue 1, 2020 · pp. 31–43 Read article
-
Synthesis and Biological Evaluation of a Novel Schiff Base Ligand [(E)-2,4-Dichloro-6-(1-((4-Fluorophenyl) iminoethyl)phenol] and Its Metal Complexes
Abstract: The study involved the synthesis and characterization of a novel bidentate Schiff base ligand, [(E)-2,4-dichloro-6-(1-((4-fluorophenyl) iminoethyl) phenol)], derived from 1-(3,5-dichloro-2-hydroxyphenyl) ethanone and 4-fluoroaniline. Transition metal salts (Co (II), Cu (II), Fe (II), Zn (II), Ni (II), Mn (II), Ag (II), Cd (II), Hg (II), and Pd (II)) were used to synthesize metal complexes. The chemicals used were of analytical grade, and solvents were distilled before use. Characterization involved UV, IR, …
Published in International Journal of Analytical and Applied Chemistry · Vol. 10, Issue 1, 2024 · pp. 26–35 Read article
-
Green Synthesis, Characterization and Antimicrobial Studies of Ni(II) and Cu(II) Schiff Base Complexes
Abstract: Solvent-assisted mechanochemical reaction was used to synthesize new transition metal complexes of Ni(II) and Cu(II) with Schiff base ligand (H2L) obtained from condensation of 2-hydroxy-1- napthaldehyde with 2 aminobenzimidazole. Melting point/decomposition temperature, solubility test, FT-IR, powder x-ray analysis, conductivity measurement, magnetic susceptibility, elemental microanalysis, and UV/VIS spectral investigations were used to characterize the Schiff base and complexes. The complexes are of varied colours and have sharp melting points, and they …
Published in International Journal of Green Chemistry · Vol. 8, Issue 1, 2022 · pp. 9–18 Read article
-
Synthesis, Characterization and Catalytic Study of Chitosan-Schiff Base Manganese Complex
Abstract: Schiff base is the condensation product formed when a primary amine reacts with a carbonyl compound. The term Schiff base is normally applied to those compounds when they are being used as ligands to form coordination complexes with metal ions. Its formation takes place under acid or base catalysis or with heat. Vanillin Schiff base and Aspartic acid-Salicylaldehyde Schiff bases have been synthesised bycondensation reaction. The synthesized ligands were mixed …
Published in International Journal of Chemical Synthesis and Chemical Reactions · Vol. 8, Issue 1, 2022 · pp. 1–6 Read article
-
Synthesis , Characterization and Biological Activity of Schiff base Derived from Sulphanilamide and Salicylaldehyde and Its Metal Complexes
Abstract: ABSTRACT : Schiff bases are important intermediates for the synthesis of various bioactive compounds. However, various studies have shown that Schiff bases derived from biologically active ingredients present in medicinal plants are more effective in biological and medicinal activity than in its pure form. In this paper K(I), Ni (II), Mg (II), Cd (II) and Pb(II) Complexes were synthesized from Schiff bases derived from sulphanilamide and Salicylaldehyde. The ligand and …
Published in International Journal of Composite Materials and Matrices · Vol. 5, Issue 1, 2019 · pp. 21–29 Read article
-
Synthesis, Structural Elucidation, and Antimicrobial Screening of a Cobalt (II) Coordination Compound Derived from a Thiophene-Containing Schiff Base
Abstract: Abstract An N, O-chelating azomethine Schiff base ligand (HL), chemically identified as 2-{[(thiophen-2-yl) methylidene] amino} benzoic acid, was synthesized by an equimolar condensation reaction between thiophene-2-carbaldehyde and anthranilic acid in absolute ethanol in the presence of a catalytic amount of acetic acid. The corresponding cobalt (II) complex, formulated as [Co(L)₂] · 2H₂O, was prepared by refluxing two equivalents of the ligand with one equivalent of cobalt (II) acetate tetrahydrate in …
Published in International Journal of Analytical and Applied Chemistry · Vol. 12, Issue 2, 2026 · pp. 1–7 Read article
-
Synthesis, characterization of Schiff base and its pH metrically studies of transition metal complexes of N'-(3, 4-dihydroxybenzylidene) isonicotinohydrazide.
Abstract: Schiff reaction is one of the versatile reaction widely used in organic synthesis focused on the discovery & development of isoniazide Schiff base derivative N’(3,4-Dihydroxy benzylidene isonicotinohydrazide) have been reported in presence of 0.01g molecular iodine catalyst stirring give fast product & good yield. The synthesized compound is characterized by FTIR & H-NMR analysis. For the development of coordination chemistry Schiff base & metal ion having played most important role, …
Published in International Journal of Chemical Synthesis and Chemical Reactions · Vol. 6, Issue 2, 2020 · pp. 39–47 Read article
-
Synthesis and Antimicrobial Activity of Schiff base metal complexes derived from Ampicillin with Vanillin
Abstract: ABSTRACT: Metal -drug complexes compounds are more popular nowadays due to their greater biological activity than uncompleted legends of some drugs. However various studies have shown that Schiff base derived from biologically active ingredients present in natural materials in its pure form. In this paper K(I), Pb(II), Sr(II), Co(III), and Ba(II) complexes were synthesized from Schiff base derived from ampicillin and vanillin. The ligand and metal complexes have been screened …
Published in International Journal of Composite Materials and Matrices · Vol. 5, Issue 1, 2019 · pp. 15–20 Read article
-
Syenthesis characterization and biological activities of Schiff base metal complexes of Zr (II) Ba(II), Cu(II), Sr(II) and Th (II) derived from sulfa pyridine
Abstract: Abstract : The Schiff base ligand was prepared by sulfapyridine with salicylaldehyde Zr(II), Ba(II), Co(II), Sr(II) and Th (II) complexes of above ligand was synthesized as well. The synthesized complexes have been characterized by powder XRD and SEM. The anti microbial activity of synthesized ligand ant its complexes have been tested for their antibacterial activity against bacterial species, such as Bacillus subtilis, staphylococcus aureus, Pseudomonas, aeruginosa, Enterobacter aerogenes, E-coli and …
Published in International Journal of Polymer Science and Engineering · Vol. 5, Issue 1, 2019 · pp. 30–37 Read article
-
Preparation and Characterisation of the Schiff’s Base Complex [Pt(dpq)Cl2]
Abstract: Preparation of platinum complex [Pt(dpq)Cl2] and characterization of the complex by IR, UV, CHN and NMR techniques. DPQ ligand is obtained by 1,10 phenanthroline made react with NaBr, nitrating mixture followed by ethylenediamine in ethanol. Keywords: DPQ, intercalator, platinum complex, Schiff’s base
Published in International Journal of Chemical Synthesis and Chemical Reactions · Vol. 1, Issue 2, 2015 Read article
-
Synthesis and Characterization of Poly(etherdiphenylene terephthalamide)-Metal Complexes in Heterogeneous Medium
Abstract: Condensation of terephthalic acid and 4,4ʹ-diaminodiphenyl ether resulted in aminoterminated oligomeric poly(etherdiphenylene terephthalamide) (PODTA) using phosphorylation technique. Schiff base complexes of this polyamide were synthesized with salicylaldehyde and 2-hydroxy-1-naphthaldehyde complexes of Co(II),Ni(II) and Cu(II). All the synthesized polyamide as well as Schiff’s base complexes were characterized by elemental analysis, IR spectroscopy and magnetic susceptibility measurements. Thermal stabilities of ligand and its various complexes were compared by thermogravimetric analysis. While, Co(II) …
Published in International Journal of Polymer Science and Engineering · Vol. 2, Issue 1, 2016 · pp. 13–19 Read article
-
Synthesis, Spectral characterization and biocidal activities of Triphenyl antimony (V) halide and methoxide complexes
Abstract: The schiff base ligands N-mono(salicyclidene)-σ-phenylenediamine (spdH) and N-mono(2-hydroxy-1-naphthalidene)-σ-phenylenediamine (hnpdH) and their triorganoantimony (V) complexes were synthesized by conventional method, were characterized by UV, IR and 1H NMR spectral studies which proposed that in the complexes of the ligands spdH and hnpdH, antimony is seven coordinated and in sp3d3 hybridization state with pentagonal bipyramidal geometry. Keywords: halide, methoxide complexes, triphenylantimony (V)
Published in International Journal of Chemical Synthesis and Chemical Reactions · Vol. 3, Issue 1, 2017 Read article
-
Review on Azomethine-Compounds with Their Applications
Abstract: Azomethine derivatives are very important and the initiating compound for most synthetic chemistrycompounds in all their fields. Since R, R1 is an alkyl or aryl group, the first to prepare and isolate itwas the German scientist Hugo Schiff in 1864 from the condensation of the carbonyl group (aldehyde,ketone) with a primary amine compound (aliphatic, aromatic). During the past few decades there hasbeen great interest in Schiff base compounds. The rules …
Published in International Journal of Chemical Synthesis and Chemical Reactions · Vol. 7, Issue 2, 2021 · pp. 1–10 Read article
-
Preparation of Beta Lactam Compounds and Study of Thermodynamically Behavior
Abstract: Several Lactam derivatives have been prepared by condensation reaction of folic acid with (4-chloroacetophenone and 4-hydroxyacetophenone) in ethanol. Then the resultant compounds (1,2) react with another Schiff bases by reacting of 4- bromobenzaldehyde with an amino acid (Phenylalanine, Tryptophan, Tyrosine and Histidine) to give bis-β-lactam rings. The structures of target compounds were characterized by many spectroscopic methods including NMR, FTIR technique and their melting points. The β- lactam derivatives were …
Published in International journal of Thermodynamics and Chemical Kinetics · Vol. 5, Issue 2, 2019 · pp. 9–15 Read article
-
Synthesis and Evaluation of Antimicrobial Activity of Some Heterocyclic Moieties of Pyrazole Derivatives
Abstract: In a successful trial to synthesize pyrazole derivatives, acetophenone was, first, reacted with phenylhydrazine producing the Schiffs’s base condensation product (E)-1-phenyl-2-(2-phenylethylidene) hydrazine 1. The application of Vilsmeier Haack’s reaction on this product afforded the cyclization product (1,3-diphenyl-1H-pyrazole-4-carbaldehyde 2 as a pyrazole derivative in good yield percentage. The treatment of (1,3-diphenyl-1H-pyrazole-4-carbaldehyde (2) with acetophenone results in the formation of another pyrazole derivative (3), having a chalcone moiety.The chemical structure of newly …
Published in International Journal of Chemical Synthesis and Chemical Reactions · Vol. 10, Issue 1, 2025 · pp. 26–36 Read article