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60 articles for “Metal Complexes”
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Synthesis and Biological Evaluation of a Novel Schiff Base Ligand [(E)-2,4-Dichloro-6-(1-((4-Fluorophenyl) iminoethyl)phenol] and Its Metal Complexes
Abstract: The study involved the synthesis and characterization of a novel bidentate Schiff base ligand, [(E)-2,4-dichloro-6-(1-((4-fluorophenyl) iminoethyl) phenol)], derived from 1-(3,5-dichloro-2-hydroxyphenyl) ethanone and 4-fluoroaniline. Transition metal salts (Co (II), Cu (II), Fe (II), Zn (II), Ni (II), Mn (II), Ag (II), Cd (II), Hg (II), and Pd (II)) were used to synthesize metal complexes. The chemicals used were of analytical grade, and solvents were distilled before use. Characterization involved UV, IR, …
Published in International Journal of Analytical and Applied Chemistry · Vol. 10, Issue 1, 2024 · pp. 26–35 Read article
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Redox system initiated improved low-temperature colouration of real silk with metal-complex dyes for energy conservation
Abstract: Silk has always been the symbol of royalty due to its lustrous appearance and peach like softness. It can be dyed in bright shades with the available natural and many synthetic dyestuffs. The slight cationic character of silk makes it possible to be dyed with anionic synthetic dyes such as acid, metal complex, reactive and selected direct dyes. The main objective of colouration of a textile fibre should be to …
Published in International Journal of Green Chemistry · Vol. 2, Issue 1, 2016 · pp. 9–17 Read article
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Anti-tubercular activity of dioxo molybdenum (VI) metal complexes of 2-((E)-(1,5-dimethyl-2-phenyl-3-((Z)-(quinoline-8-ylimino)methyl)-2,3-dihydro-1H-pyrazole-4-ylimino)methyl)phenol
Abstract: Dioxomolybdenum(VI) complexes tetradentate ligand 2-((E)-(1,5-dimethyl-2-phenyl-3-((Z)-(quinoline-8-ylimino)methyl)-2,3-dihydro-1H-pyrazole-4-ylimino)methyl)phenol was synthesized by conventional method The ligands and their MoO22+ complexes have been characterized on the basis of elemental analysis, electronic. I.R., 1H and 13C-NMR spectral method, by their spectral studies, octahedral geometry of the complex has been proposed. On evaluation of in-vitro antitubercular activity of the ligand and dioxo Mo(VI) metal complex found that complex is more potent antitubercular agent than ligand. Keywords: anti-tubercular …
Published in International Journal of Chemical Synthesis and Chemical Reactions · Vol. 3, Issue 1, 2017 Read article
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Synthesis and Antimicrobial Activity of Schiff base metal complexes derived from Ampicillin with Vanillin
Abstract: ABSTRACT: Metal -drug complexes compounds are more popular nowadays due to their greater biological activity than uncompleted legends of some drugs. However various studies have shown that Schiff base derived from biologically active ingredients present in natural materials in its pure form. In this paper K(I), Pb(II), Sr(II), Co(III), and Ba(II) complexes were synthesized from Schiff base derived from ampicillin and vanillin. The ligand and metal complexes have been screened …
Published in International Journal of Composite Materials and Matrices · Vol. 5, Issue 1, 2019 · pp. 15–20 Read article
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Synthesis and Characterization of Poly(etherdiphenylene terephthalamide)-Metal Complexes in Heterogeneous Medium
Abstract: Condensation of terephthalic acid and 4,4ʹ-diaminodiphenyl ether resulted in aminoterminated oligomeric poly(etherdiphenylene terephthalamide) (PODTA) using phosphorylation technique. Schiff base complexes of this polyamide were synthesized with salicylaldehyde and 2-hydroxy-1-naphthaldehyde complexes of Co(II),Ni(II) and Cu(II). All the synthesized polyamide as well as Schiff’s base complexes were characterized by elemental analysis, IR spectroscopy and magnetic susceptibility measurements. Thermal stabilities of ligand and its various complexes were compared by thermogravimetric analysis. While, Co(II) …
Published in International Journal of Polymer Science and Engineering · Vol. 2, Issue 1, 2016 · pp. 13–19 Read article
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Synthesis , Characterization and Biological Activity of Schiff base Derived from Sulphanilamide and Salicylaldehyde and Its Metal Complexes
Abstract: ABSTRACT : Schiff bases are important intermediates for the synthesis of various bioactive compounds. However, various studies have shown that Schiff bases derived from biologically active ingredients present in medicinal plants are more effective in biological and medicinal activity than in its pure form. In this paper K(I), Ni (II), Mg (II), Cd (II) and Pb(II) Complexes were synthesized from Schiff bases derived from sulphanilamide and Salicylaldehyde. The ligand and …
Published in International Journal of Composite Materials and Matrices · Vol. 5, Issue 1, 2019 · pp. 21–29 Read article
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Syenthesis characterization and biological activities of Schiff base metal complexes of Zr (II) Ba(II), Cu(II), Sr(II) and Th (II) derived from sulfa pyridine
Abstract: Abstract : The Schiff base ligand was prepared by sulfapyridine with salicylaldehyde Zr(II), Ba(II), Co(II), Sr(II) and Th (II) complexes of above ligand was synthesized as well. The synthesized complexes have been characterized by powder XRD and SEM. The anti microbial activity of synthesized ligand ant its complexes have been tested for their antibacterial activity against bacterial species, such as Bacillus subtilis, staphylococcus aureus, Pseudomonas, aeruginosa, Enterobacter aerogenes, E-coli and …
Published in International Journal of Polymer Science and Engineering · Vol. 5, Issue 1, 2019 · pp. 30–37 Read article
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Synthesis, characterization of Schiff base and its pH metrically studies of transition metal complexes of N'-(3, 4-dihydroxybenzylidene) isonicotinohydrazide.
Abstract: Schiff reaction is one of the versatile reaction widely used in organic synthesis focused on the discovery & development of isoniazide Schiff base derivative N’(3,4-Dihydroxy benzylidene isonicotinohydrazide) have been reported in presence of 0.01g molecular iodine catalyst stirring give fast product & good yield. The synthesized compound is characterized by FTIR & H-NMR analysis. For the development of coordination chemistry Schiff base & metal ion having played most important role, …
Published in International Journal of Chemical Synthesis and Chemical Reactions · Vol. 6, Issue 2, 2020 · pp. 39–47 Read article
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Green Synthesis, Characterization and Antimicrobial Studies of Ni(II) and Cu(II) Schiff Base Complexes
Abstract: Solvent-assisted mechanochemical reaction was used to synthesize new transition metal complexes of Ni(II) and Cu(II) with Schiff base ligand (H2L) obtained from condensation of 2-hydroxy-1- napthaldehyde with 2 aminobenzimidazole. Melting point/decomposition temperature, solubility test, FT-IR, powder x-ray analysis, conductivity measurement, magnetic susceptibility, elemental microanalysis, and UV/VIS spectral investigations were used to characterize the Schiff base and complexes. The complexes are of varied colours and have sharp melting points, and they …
Published in International Journal of Green Chemistry · Vol. 8, Issue 1, 2022 · pp. 9–18 Read article
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COMPLEXATION AND ANTIBACTERIAL STUDY OF 1,3,4-OXADIAZOLE DERIVATIVE
Abstract: New metal complexes of Zn(II),and Ni(II) have been synthesized by reacting metal solutions with the ligand 2,5-substituted 1,3,4-Oxadiazoles in alcoholic medium. Molecular formulae of the complexes were determined and are further characterized by IR spectroscopy, magnetic susceptibility and molar conductance studies. Since two nitrogen atoms coordinate to the metal center, the ligand is termed as bidentate ligand.KEY WORDS: Complexes, Ligands, Transition metal complexes, Oxadiazoles.
Published in International Journal of Green Chemistry · Vol. 6, Issue 2, 2020 · pp. 26–29 Read article
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Synthesis and Characterization of Mixed Ligand Complexes of Hydroxamic Acids with Metal (II) Phthalimide
Abstract: The mixed ligand complexes of Co (II) and Ni (II) with potassium salt of phthalimide (primary ligand) and hydroxamic acids (secondary ligand), where hoxm = L1=3,4,5-trimethoxy benzohydroxamic acids (TMBHA), L2=N-phenyl–3,4,5-trimethoxy benzohydroxamic acid (PTMBHA), L3=3,4-di methoxy benzohydroxamic acid (DMBHA) and L4=N-phenyl-3,4-di methoxy benzohydroxamic acid (PDMBHA) and phth=phthamlimide were synthesized and characterized by elemental analysis, melting points, I.R studies, UV–visible analysis, measurement of magnetic susceptibility, thin layer chromatography, etc. Elemental analysis depicts …
Published in International journal of Thermodynamics and Chemical Kinetics · Vol. 3, Issue 1, 2017 · pp. 1–6 Read article
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Synthesis, Characterization and Catalytic Study of Chitosan-Schiff Base Manganese Complex
Abstract: Schiff base is the condensation product formed when a primary amine reacts with a carbonyl compound. The term Schiff base is normally applied to those compounds when they are being used as ligands to form coordination complexes with metal ions. Its formation takes place under acid or base catalysis or with heat. Vanillin Schiff base and Aspartic acid-Salicylaldehyde Schiff bases have been synthesised bycondensation reaction. The synthesized ligands were mixed …
Published in International Journal of Chemical Synthesis and Chemical Reactions · Vol. 8, Issue 1, 2022 · pp. 1–6 Read article
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Theoretical Investigation of the Interactions between Cytochrome C and Some Heavy Metal Ions: A Biophysical Analysis
Abstract: Cytochrome c is located in mitochondria and has an important role in ATP synthesis. In addition to this, this molecule plays an important role in the conversion to water molecule of molecular oxygen. Using chemical equalization principles about chemical hardness and electronegativity concepts, the power of the interactions between chemical compounds, metals and ligands. In the present study, we theoretically analyzed electron transfer mechanisms and the power of the interactions …
Published in International Journal of Industrial Biotechnology and Biomaterials · Vol. 5, Issue 2, 2019 · pp. 27–31 Read article
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SYNTHESIS AND CHARACTERIZATION OF MIXED LIGAND COMPLEXES OF HYDROXAMIC ACIDS WITH POTASSIUM HEXATHIOCYANATO CHROMIUM (III) TETRA HYDRATE
Abstract: Some hydroxamic acids eg.[L1= benzohydroxamic acids (BHA), L2= N-phenyl– benzohydroxamic acid (NPBHA), L3= pivaloyl benzohydroxamic acid (PHA) and L4=N-phenyl-pivaloyl benzohydroxamic acid (PPHA) prepared and reacted with L’=Potassium hexathiocynato chromium (III) tetra hydrate K3[Cr(SCN)6]4H2O.The mixed ligand complexes of hydroxamic acids characterized with the help of repeated melting point, by I.R. studies, magnetic moment, molar conductance and by elemental analysis(C,H and N).The stoichiometry of the complexes were found to be 1:2(M:L) molar …
Published in International Journal of Chemical Synthesis and Chemical Reactions · Vol. 2, Issue 2, 2016 Read article
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Synthesis, Spectral and Magnetic Moment Studies of Mixed Ligand Complexes of Hydroxamic Acids with Potassium Hexathiocyanato Vanadium (II) Tetra Hydrate
Abstract: Preparation and characterization of several hydroxamic acids of 3,4,5-trimethoxy benzohydroxamic acids(TMBHA), N-phenyl–3,4,5-trimethoxy benzohydroxamic acid(PTMBHA), 3,4-dimethoxy benzohydroxamic acid(DMBHA) and N-phenyl-3,4-dimethoxy benzohydroxamic acid(PDMBHA) were prepared and reacted with potassium hexathiocynato vandate (II) K4[V(NCS)6].3H2O tetra hydrate. The mixed ligand complexes of hydroxamic acids characterized with the help of repeated melting point identification, by I.R. studies, magnetic moment, molar conductance’s and by elemental analysis (C, H and N). The geometry of complexes were found …
Published in International Journal of Chemical Synthesis and Chemical Reactions · Vol. 2, Issue 2, 2016 Read article
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Heavy Metals in Soil and Their Impact on Plant Health: A Contamination Study
Abstract: This study investigates heavy metal uptake, tolerance, and sequestration mechanisms in various plants, focusing on crops, such as tea, vegetables, and fruit trees that are susceptible to heavy metal contamination. Trace elements in plants, if overabundant, pose toxicity risks by disrupting metabolic and physiological functions. Plants counteract heavy metal complexes by immobilizing them within cell walls or vacuoles or by binding them to organic compounds produced in situ. Elevated levels …
Published in International Journal of Agrochemistry · Vol. 10, Issue 2, 2024 · pp. 7–12 Read article
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Heavy Metals in Soil and Their Impact on Plant Health: A Contamination Study
Abstract: This study investigates heavy metal uptake, tolerance, and sequestration mechanisms in various plants, focusing on crops such as tea, vegetables, and fruit trees that are susceptible to heavy metal contamination. Trace elements in plants, if overabundant, pose toxicity risks by disrupting metabolic and physiological functions. Plants counteract heavy metal complexes by immobilizing them within cell walls or vacuoles or by binding them to organic compounds produced in situ. Elevated levels …
Published in International Journal of Agrochemistry · Vol. 10, Issue 2, 2024 Read article
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Cognitive Metallurgy: A Study on Microstructure and Energy Efficiency in High-Temperature Alloying via Sensor Fusion and Deep Reinforcement Learning
Abstract: Background Traditional high-temperature metallurgical processes, such as continuous casting and specialty alloy synthesis, are characterized by high energy consumption, stochastic variability, and reliance on post-process defect inspection. The inability to precisely monitor, model, and predict the real-time thermal, chemical, and mechanical state of molten metal and cooling substrates results in significant material waste and inconsistent microstructural integrity. Methodology This study introduces a novel framework for Cognitive Metallurgy utilizing an integrated …
Published in International Journal of Metallurgy and Alloys · Vol. 11, Issue 2, 2025 · pp. 27–36 Read article
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Chemical Synthesis Strategies and Reaction Mechanisms in Self-Healing Polymeric Materials: A Comprehensive Review
Abstract: Self-healing polymeric materials are one of the most rapidly growing and technologically transformative classes of smart polymeric materials. Such materials offer the ability to autonomously repair damage and retain & restore functional performance. This capability is very important for polymers, which undergo mechanical failure, micro- cracking, delamination, photo-oxidation, or thermal degradation during service environments. The last decade has been remarkable for developments in self-healing polymers, ranging from extrinsic capsule-based approaches …
Published in International Journal of Chemical Synthesis and Chemical Reactions · Vol. 12, Issue 1, 2026 · pp. 26–34 Read article
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Kinetics of Oxidation of L-Proline by Hexacyanoferrate (III) Ion in Presence of Os (VIII)
Abstract: Amino acids are building block of proteins and maintaining a vital role in growth of human beings as well as animals. Amino acids may form metal complexes and other complexes in animal and human body. Therefore, the study of oxidation of amino acids as well as their complexes is interesting area for academicians and physicians. Amino acids are the compounds of two functional groups -NH2 and –COOH. Hence depending on …
Published in International Journal of Chemical Engineering and Processing · Vol. 7, Issue 1, 2021 · pp. 12–24 Read article