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149 articles for “Activation Energy”
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Studies on the Kinetics of Thermal Decomposition of Copper Oxalate Mixed With Silver Oxalate
Abstract: The coprecipitates, Ag2Cu(C2O4)nH2O of varying composition [Ag = (1 and 2)%], have been synthesized and were characterized by means of IR, XRD, and SEM. The decomposition of the prepared oxalates was monitored by differential scanning calorimetry (DSC) and thermogravimetry (TG). The DSC studies reveal that the decompositions of the mixed oxalates were all complex exothermic processes with resemblance to the exothermic reaction of copper oxalate and ranges from 540 to …
Published in International journal of Thermodynamics and Chemical Kinetics · Vol. 2, Issue 1, 2016 · pp. 1–11 Read article
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Synthesis, Characterization and Photoconductive Properties of Antimony Selenium Iodide
Abstract: A shiny needle-shaped polycrystalline chalcogenide compound, SbSeI, was synthesized through a solid-state thermal reaction by combining the constituent elements in a stoichiometric ratio within an evacuated quartz tube at 585°C for 3.5 hours. The resulting compound was characterized using SEM, EDAX, and XRD techniques to confirm its structure and composition. The resistance versus temperature curve revealed the semiconducting nature of the material with a resistivity of 3.5 x 10⁷ Ω-cm …
Published in International Journal of Chemical Synthesis and Chemical Reactions · Vol. 10, Issue 1, 2025 · pp. 1–8 Read article
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Kinetic Modeling of Biomass Pyrolysis for Renewable Energy Production.
Abstract: Biomass pyrolysis is a promising technology for renewable energy production, offering a sustainable alternative to fossil fuels. This process involves the thermal decomposition of organic materials in the absence of oxygen, resulting in the generation of bio-oil, syngas, and biochar. Kinetic modeling of biomass pyrolysis is essential for optimizing the process and enhancing the yield and quality of the products. This abstract presents a comprehensive review of kinetic models used …
Published in International journal of Thermodynamics and Chemical Kinetics · Vol. 10, Issue 1, 2024 · pp. 1–6 Read article
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A method to determine kinetic triplet by coupled with model-free method and model-fitting method
Abstract: The present study is aimed to obtain integral linear method using rational expressions given by Senum and Yang, and a method of selecting the reaction model more quickly and easily and compute the activation energy and pre- exponential factor more accurately was proposed. An improved linear integral procedure coupled with one model-free method and one model-fitting method for the determination of kinetic triplet using non-isothermal data recorded at several heating …
Published in International journal of Thermodynamics and Chemical Kinetics · Vol. 11, Issue 1, 2025 · pp. 1–13 Read article
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Mathematical Modeling of Mass Transfer of Heavy Metals from the Diffusion of Condemned Oil in Soil Environment
Abstract: The diffusion and reaction kinetics of heavy metals in soil are critical factors influencing pollutant migration and environmental remediation strategies. Understanding the diffusion and reaction kinetics of heavy metals in soils is crucial for assessing environmental contamination and designing effective remediation strategies. This study investigated the diffusion behavior of heavy metals in soil media under varying thermal and physical conditions, employing a first- order reaction model based on Fick’s second …
Published in International Journal of Analytical and Applied Chemistry · Vol. 11, Issue 2, 2025 Read article
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Thermodynamic and Kinetic Characterization of Aluminum Corrosion and Inhibition Adsorption of Vernonia Amygdalina Fruit Extract IN 0.5N H2SO4
Abstract: Anti-corrosive efficacy of ethanolic extract of Vernonia amygdalina fruit extract on corrosion of aluminum in 0.5N H2SO4 acidic solution was explored by mass loss measurement at rise in temperature between 303-343 K for 24 hours immersion period. The I.E. (η%) has been noticed prominently high (62.92%) at concentration 0.45% at 303 K. An inhibitor adsorption on the surface aluminum have been found to be best fitted Langmuir adsorption isotherm. It …
Published in International journal of Thermodynamics and Chemical Kinetics · Vol. 9, Issue 1, 2023 · pp. 20–27 Read article
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Pyrolysis Characteristics and Isoconversional kinetics of kusum deoiled seedcake.
Abstract: The pyrolysis characteristics and kinetics of kusum de-oiled seed cake were conducted using a Thermo gravimetric analyzer. Thermogravimetric analysis of biomass was carried out at three different heating rates of 10, 20, 30, ̊ C/min from 28 ̊ C to 1000 ̊ C under N2 atmosphere. The results indicated that the biomass was decomposed in the temperature range of 270 ̊C to 520 ̊ C and further decreased when temperature …
Published in International Journal of Environmental Chemistry · Vol. 2, Issue 2, 2016 · pp. 9–17 Read article
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An overview of current activities in commercial deployment of hydrogen energy projects around the world
Abstract: Hydrogen energy systems have been proposed as one of the major components of a decarbonized, clean and sustainable energy system of the future, which will also include renewables, nuclear energy and biomass energy forms. Hydrogen production, storage, distribution and re-conversion technologies are essential components of this value chain. This study looks at some commercial level technologies available and projects deployed round the world for ushering in hydrogen energy systems on …
Published in International Journal of Renewable Energy and its Commercialization · Vol. 6, Issue 2, 2020 · pp. 16–25 Read article
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Kinetic and Mechanistic Study of Isomenthol Oxidation by Trichloroisocyanuric Acid in Acidic Medium
Abstract: The oxidation reaction of isomenthol with trichloroisocyanuric acid (TCICA) was systematically investigated in acidic medium to understand its kinetics, reaction mechanism, and overall reactivity. The study was carried out under pseudo-first-order conditions by maintaining a large excess of isomenthol relative to TCICA, allowing accurate determination of the reaction rate. The progress of the oxidation reaction was monitored kinetically, and the obtained data revealed that the reaction follows first-order kinetics with …
Published in International Journal of Chemical Synthesis and Chemical Reactions · Vol. 12, Issue 2, 2026 · pp. 1–7 Read article
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Mechanistic Insights into Solvent-Controlled Stepwise and Concerted Cycloadditions of the Propadienyl Cation with Oxoamides: A DFT Study
Abstract: AbstractOxazoles constitute an important class of heterocycles with widespread applications in medicinal chemistry and materials science, yet the mechanistic features governing their formation via cationic cycloaddition reactions remain incompletely understood. In this work, we present a comprehensive density functional theory (DFT) investigation into the reaction between the propadienyl cation and oxoamides as a model system for oxazole ring formation. Using the CAM-B3LYP/6–31+G(d,p) level of theory, we systematically compare gas-phase reactivity …
Published in International journal of Thermodynamics and Chemical Kinetics · Vol. 12, Issue 1, 2026 · pp. 8–17 Read article
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Evaluation of Adsorption Isotherm Parameters on Corrosion Rate of Metal using Water-Based Extracts as an Inhibitor in Acidic Medium
Abstract: The research showcases the evaluation of MCS metal corrosion rate in terms of the effect of temperature and adsorption isotherm parameters monitored using water-based extracts with the aim to predict the Gibb’s free energy characteristics on inhibition integrity of the metal sample in acidic medium of 1.0M of HCl The water-based extract used are Selaginella myosurus, SM and Pneumatopter is pennigera, GF and the inhibition performance with respect to temperature …
Published in International Journal of Polymer Science and Engineering · Vol. 9, Issue 1, 2023 · pp. 14–25 Read article
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Invitro Studies on Isolation, Screening and Characterization of Streptokinase from Bacillus SPP
Abstract: Streptokinase have isolated from the Bacillus spp. by using fermentation. The soil sample have collected from the different area of the Lucknow. The Gram’s staining was used to determining Bacillus spp. The screening method was used for the characterization for the bacteria. The enzyme concentration measured by using Lowry’s protein estimation method. Caseinolytic activity have performed to study the enzyme activity. Many different enzymes are required to bring about the …
Published in International Journal of Green Chemistry · Vol. 8, Issue 1, 2022 · pp. 19–35 Read article
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Study of Corrosion and Corrosion Protection of Rebar Steel in Saline water
Abstract: Corrosion is major problem with metals. When they come in contact of surrounding corrosive medium to construct a corrosion cell on their interface, metals undergo in corrosion reactions. Such environments metals can be exhibited uniform, galvanic, pitting, stress, crevice, embrittlement, intergranular corrosion etc. The corrosion of phenomenon of rebar steel studied in saline water. It creates corrosive medium for rebar steel due to availability of chloride ions. Rebar steel is …
Published in International Journal of Metallurgy and Alloys · Vol. 11, Issue 2, 2025 · pp. 1–11 Read article
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Hydrogenation of dimethyl-nitrobenzene to dimethyl-aniline in a three-phase Reactor
Abstract: The liquid-phase catalytic hydrogenation of dimethyl-nitrobenzene (DN) to Dimethyl-aniline (DA) was carried out in ethanol using 5% Pd/C as a catalyst. The effects of hydrogen partial pressure (400–1000 kPa), reaction temperature (343–403 ), catalyst loading (5–15 g/lit), speed of stirring range (200-800 rpm) and dimethyl-nitrobenzene concentration (0.12–0.75 mol/lit) on the hydrogenation of dimethyl-nitrobenzene and the yield of Dimethyl-aniline have been studied. Dimethyl-aniline was the only reaction product, generated through the …
Published in International Journal of Chemical Separation Technology · Vol. 3, Issue 2, 2017 · pp. 1–13 Read article
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Production of Waste Animal Bone as a Heterogeneous Solid Base Catalyst for Transesterification of Jatropha Oil
Abstract: Heterogeneous catalyst plays a vital role in transesterification process, especially in view of cost and reusability. In this study, heterogeneous solid base catalyst was prepared by impregnating the waste animal bone with different weight percent (wt%) KOH solution followed by drying and calcination at 900 °C for 3 hr. Having screened the catalytic performance and basicity of animal bone loaded with different K-compounds, 12 wt% KOH loaded on animal bone …
Published in International Journal of Chemical Separation Technology · Vol. 5, Issue 1, 2019 · pp. 28–48 Read article
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Kinetic and Thermodynamic Studies of Adsorption of Pb (II) by Using Ferrous Sulphide as an Adsorbent
Abstract: Poisoning of lead is causing a serious threat to the environment. In the present study the adsorption behaviour of lead was studied in detail by ferrous sulphide in granular form. Ferrous sulphide has the magnetic properties and makes it a better candidate for lead removal. Batch adsorption experiments were carried out by varying different process parameters such as contact time, adsorbent dose, pH, and temperature. Lead adsorption by ferrous sulphide …
Published in International Journal of Chemical Engineering and Processing · Vol. 2, Issue 2, 2016 · pp. 33–41 Read article
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Catalytic hydrogenation of dimethyl-nitrobenzene to dimethyl-aniline over Ni catalysts
Abstract: The catalytic transfer hydrogenation of dimethyl-nitrobenzene (DN) to Dimethyl-aniline (DA) was studied in the temperature range 343–403 , pressure range of 4–10 bar H2 and ethanol as solvent using Ni on alumina-silicate as catalyst above agitation speed 800 rpm. The substrate feed concentration was varied in the range from 0.124 to 0.745 kmol/m3 while catalyst loading was in the range 4–12% (w/w) of dimethyl-nitrobenzene. Dimethyl-aniline was the only reaction product, …
Published in International Journal of Chemical Engineering and Processing · Vol. 3, Issue 2, 2017 · pp. 19–29 Read article
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Nanocoating and Electrospraying Techniques Used for Corrosion Mitigation of Aluminum in Nitrogen dioxide Environment
Abstract: Nitrogen gas absorbs moist air to produce nitric acid. It develops acidic medium for aluminum. It forms a corrosion cell on the surface of aluminum. The formation of corrosion cell is written as: Al|Al+3||H+|H2 thus Corrosion reactions accelerate on aluminum surface and Al is oxidized into Al+3 and the H+ ions is reduced into H2. This acid produces various forms of corrosion in aluminum like galvanic, pitting, stress, crevice, blistering, …
Published in International Journal of Environmental Chemistry · Vol. 6, Issue 2, 2020 · pp. 20–31 Read article
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Mechanical Studies and Thermal Kinetics of Isoniazid Crystals
Abstract: Single crystals of isoniazid were crystallized by slow solvent evaporation method. The crystal structure was confirmed using single crystal X-ray diffraction analysis. Micro hardness was estimated and work hardening coefficient and Newtonian resistance pressure of the crystal were determined. Kinetic analysis of the thermogravimetric data was carried out by using Coats-Redfern relation. Activation energy, frequency factor and order of reaction were also calculated. Arrhenius equation for isoniazid is k=0.43×105e–79103/RT mol–1s–1. …
Published in International Journal of Chemical Synthesis and Chemical Reactions · Vol. 1, Issue 1, 2015 Read article
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Valorization of agro-industrial waste into bioethanol: a case of brewers spent grain
Abstract: AbstractThe global impetus to produce alternatives to petroleum-based fuels and value-added chemicals to reduce greenhouse gases are putting pressure on the industries to diversify and valorize byproducts. By-products valorization of the brewery industry such as spent grain has given critical attention for long-term socio-economic and environmental benefits. Brewer`s spent grain is the major by-product of the brewing industry, represses around 85% of the total by-product generated. In the current work, …
Published in International Journal of Renewable Energy and its Commercialization · Vol. 6, Issue 1, 2020 · pp. 1–20 Read article