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54 articles for “kinetic models”
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Investigation into the Kinetics of Biodegradation of Crude Oil Hydrocarbon in Different Soil Types Using Aloe Vera
Abstract: A pilot study was conducted on three different soil type contaminated with crude oil bio-simulated with Aloe vera juice to examine the effect of the stimulant on the rate of degradation of the crude oil by the indigenous microbes. Soil contaminated with crude is deficient of the essential nutrients which are needed to boast the activities of the microbes which feed on the crude. These nutrients are found in Aloe …
Published in International Journal of Chemical Synthesis and Chemical Reactions · Vol. 4, Issue 2, 2018 · pp. 10–21 Read article
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CFD on Parametric Analysis of Compression Ignition Engine by using Star CCM+
Abstract: Stringent emission from the conventional vehicles draws attention of automobile researches to develop engine either high fuel efficiency and low emission of NOx, CO and unburnt hydrocarbons. Hence, there by Homogeneous charge compression ignition came to the effect. Homogeneous charge compression ignition engine is the type of engine the well organised mixture of air and fuel ratio enters into the combustion chamber, and it is compressed up to auto-ignited temperature …
Published in International Journal of I.C. Engines and Gas Turbines · Vol. 7, Issue 2, 2021 · pp. 27–66 Read article
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Review of Reactive Extraction Process for Recovery of Pyruvic Acid
Abstract: Pyruvic acid having a molecular formula (C3H4O3) is an important alpha-keto-carboxylic acid. It is mainly manufactured by biotechnological routes or chemical synthesis. There are number of applications of pyruvic acid in the industrial sector such as chemical, food, cosmetic and agriculture sector. The main problem for the production of pyruvic acid from the fermentation broth is downstream processing. The number of techniques developed to recover this acid from their aqueous …
Published in International journal of Thermodynamics and Chemical Kinetics · Vol. 4, Issue 2, 2018 · pp. 1–7 Read article
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Simulation of Heat Generated on Crude Oil Degradation upon the Effect of Temperature in Bacteria Growth Kinetics in a Bioreactor
Abstract: Model was established to simulate the heat generated by bacteria with the interaction of substrate (crude oil) degradation in a bioreactor upon the influence of temperature. The model was predicted by simulating the characteristics of bacteria interaction with substrate at temperature of 15oC, 30oC, 45oC, 60oC, 75oC, 90oC, 105oC and 120oC and heat generated is within the range of -1.0 to 7.1kcal/hr for bacteria in fresh water medium whereas for …
Published in International journal of Thermodynamics and Chemical Kinetics · Vol. 8, Issue 2, 2022 · pp. 39–54 Read article
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Predicting the TPH Concentration along Horizontal Direction of Stagnated Water Contaminated with Crude Oil
Abstract: The research predicts and models TPH concentration along Horizontal Direction of Stagnated water contaminated with Crude Oil. TPH diffusion in the stagnant water media was studied using Developed Dispersion and Degradation Model incorporated with first order degradation rate and the Monod equation. TPH content decreased with increase in time, but randomly varied across the depths. The impact of crude oil was more in the fresh water compared to salt water …
Published in International Journal of Chemical Separation Technology · Vol. 9, Issue 1, 2023 · pp. 12–22 Read article
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Synthesis and Characterization of Poly(vinylpyrrolidone) / Starch / Dimethylacrylamide Hydrogel by Gamma Radiation and Its Application in Basic Fuchsin and Methyl Orange Removal
Abstract: Gamma radiation was used to create a number of PVP/Starch/Dimethylacrylamide (PSD) based hydrogels. Investigated were the effects of several parameters, such as radiation dose, material composition, and pH, on the characteristics of hydrogels, such as gel content and swelling behavior. Radiation doses ranged from 10 to 25 kGy, and 10 kGy was determined to be the ideal dose. Investigations on the impact of dimethylacrylamide (DMA) composition on swelling were investigated. …
Published in International Journal of Polymer Science and Engineering · Vol. 9, Issue 2, 2023 · pp. 1–20 Read article
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Application of Monod Equation and First Order RateKinetics for the Determination of TPH Concentrationalong the Depths
Abstract: In order to calculate the rate of TPH concentration along the depths, this research project applies theMonod Equation and First Order Rate Kinetics. TPH diffusion in the stagnant water medium wasexamined using the Developed Dispersion and Degradation Model integrated with the first orderdegradation rate and the Monod equation q2. TBC in both water media increased gradually over timeuntil the 56th day, and then rapidly between the 70th and 80th day. …
Published in International Journal of Renewable Energy and its Commercialization · Vol. 10, Issue 1, 2024 · pp. 26–43 Read article
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Analysis of the Degradation of Total Petroleum Hydrocarbons (TPH) in a Polluted Stagnant Salt and Fresh Water Environment
Abstract: TPH dispersion in both water media was investigated using a transport model that included convective and diffusion factors. This model was used to track the TPH concentration in both vertical and horizontal dimensions. Therefore, it was expected that diffusion alone would regulate TPH transport or spreading in the x-direction, or horizontal direction, while diffusion and convection caused by gravity would control TPH transport in the vertical direction. As a result, …
Published in International Journal of Chemical Separation Technology · Vol. 9, Issue 2, 2023 · pp. 1–12 Read article
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Novel method for determination of kinetic constants from dynamics in a batch reactor with constant heat input rate
Abstract: In this article a novel method of obtaining reaction kinetic constants is described. It consists of measuring both concentration and temperature dynamics in a batch reactor supplied with a constant heat input rate. A system of esterification reaction between acetic acid and methanol in the presence of a cationic resin catalyst is studied. This reversible reaction’s rate is modeled by molecular order and as pseudo homogeneous assumption. By just one …
Published in International journal of Thermodynamics and Chemical Kinetics · Vol. 5, Issue 1, 2019 · pp. 19–23 Read article
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Fabrication of a Novel and Efficient Radiation Grafted Functionalized Polymer Adsorbent and Investigation of its Applicability in the Adsorptive Removal of Cr (VI) Ion from Aqueous Solution
Abstract: The grafting of glycidyl methacrylate (GMA) onto non-woven polyethylene (PE) fabric was accomplished using a radiation-initiated grafting technique. The grafted textiles were allowed to react using triethylamine to create functioning amine groups. Upon bond formation yield, the impact of grafting intensity has been examined. Utilizing the appropriate technologies, such as FTIR, TGA, and SEM, the adsorbents were rigorously examined. There was evidence of GMA grafting and diamines according to FTIR, …
Published in International Journal of Polymer Science and Engineering · Vol. 8, Issue 1, 2022 · pp. 1–15 Read article
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A Review of Combustion Modeling Techniques for IC Engines: CFD Simulations and Experimental Correlations
Abstract: For a long time, internal combustion (IC) engines have been the mainstay of power generating and transportation systems. However, a move toward cleaner and more efficient engine technologies has been spurred by stricter pollution restrictions and growing environmental concerns. In this context, combustion modeling has emerged as a critical tool for understanding in-cylinder processes and improving engine performance. This review focuses on the evolution and application of various combustion modeling …
Published in International Journal of I.C. Engines and Gas Turbines · Vol. 11, Issue 1, 2025 · pp. 13–20 Read article
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Kinetics of Nucleation and Growth of Metal Nanoparticles – A Mini Review
Abstract: The prediction of nucleation and growth model for metal nanoparticles is very much important in the field of catalysis and fuel cell technology. In this mini review, discuss the initial stages of nucleation and growth model for 2D and 3D instantaneous and progressive nucleation kinetics explained. Keywords: instantaneous, nucleation, nucleation rate, progressive
Published in International journal of Thermodynamics and Chemical Kinetics · Vol. 3, Issue 1, 2017 · pp. 15–18 Read article
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A Model to Study the Effect of Homogeneous Nucleation and Emulsifier Amounts on Methyl Methacrylate Emulsion Polymerization in a Seeded Semi-batch Reactor
Abstract: ABSTRACTAn extensive model is developed for methyl methacrylate emulsion polymerization. The assumption of monodispersed particle size distribution is used in developing the model. It is found that inclusion of homogeneous nucleation in the model leads to under prediction of variation of conversion with time. The effects of three different emulsifier amounts on the variation of conversion with time at 50°C isothermal reactor operation, keeping all the other ingredients constant are …
Published in International Journal of Polymer Science and Engineering · Vol. 5, Issue 2, 2019 · pp. 9–17 Read article
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Lead (II) Ion Biosorption from Aqueous Solution ontoHexadecyltriammonium Bromide (HDTMA-Br) Modified Dry Water Hyacinth
Abstract: Heavy metal release into the environment by industrial activities has become a persistent problem,with these contaminants continually increasing in concentration. Heavy metals not only circulatethrough ecosystems but also accumulate in organisms over time, which elevates their toxic effectsalong the food chain. This research was conducted to explore the efficiency of biosorption inremoving lead (II) ions from aqueous solutions using water hyacinth powder modified withhexadecyltriammonium bromide (HDTMA-Br), a cationic surfactant. The …
Published in International Journal of Chemical Synthesis and Chemical Reactions · Vol. 10, Issue 2, 2025 Read article
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Evaluation of Kinetic Parameters of Crude Oil Remediation Using Bio-Stimuant of Mint Leaf (Mentha piperita)
Abstract: Kinetic parameters of crude oil degradation as related to total petroleum hydrocarbon (TPH) were evaluated. The experiment was set-up using crude oil, loamy soil polluted and addition of bio-stimulant (nutrient based substance). The depletion of the pollutant was monitored within the contact time of 7 to 35 days. At intervals of 7 days samples were collected and analyzed to determine the TPH concentration at each bioreactor set-up, through subjecting the …
Published in International Journal of Chemical Engineering and Processing · Vol. 12, Issue 1, 2026 · pp. 62–71 Read article
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Cognitive Metallurgy: A Study on Microstructure and Energy Efficiency in High-Temperature Alloying via Sensor Fusion and Deep Reinforcement Learning
Abstract: Background Traditional high-temperature metallurgical processes, such as continuous casting and specialty alloy synthesis, are characterized by high energy consumption, stochastic variability, and reliance on post-process defect inspection. The inability to precisely monitor, model, and predict the real-time thermal, chemical, and mechanical state of molten metal and cooling substrates results in significant material waste and inconsistent microstructural integrity. Methodology This study introduces a novel framework for Cognitive Metallurgy utilizing an integrated …
Published in International Journal of Metallurgy and Alloys · Vol. 11, Issue 2, 2025 · pp. 27–36 Read article
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Hydrogenation of dimethyl-nitrobenzene to dimethyl-aniline in a three-phase Reactor
Abstract: The liquid-phase catalytic hydrogenation of dimethyl-nitrobenzene (DN) to Dimethyl-aniline (DA) was carried out in ethanol using 5% Pd/C as a catalyst. The effects of hydrogen partial pressure (400–1000 kPa), reaction temperature (343–403 ), catalyst loading (5–15 g/lit), speed of stirring range (200-800 rpm) and dimethyl-nitrobenzene concentration (0.12–0.75 mol/lit) on the hydrogenation of dimethyl-nitrobenzene and the yield of Dimethyl-aniline have been studied. Dimethyl-aniline was the only reaction product, generated through the …
Published in International Journal of Chemical Separation Technology · Vol. 3, Issue 2, 2017 · pp. 1–13 Read article
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Kinetic and Thermodynamic Studies of Adsorption of Pb (II) by Using Ferrous Sulphide as an Adsorbent
Abstract: Poisoning of lead is causing a serious threat to the environment. In the present study the adsorption behaviour of lead was studied in detail by ferrous sulphide in granular form. Ferrous sulphide has the magnetic properties and makes it a better candidate for lead removal. Batch adsorption experiments were carried out by varying different process parameters such as contact time, adsorbent dose, pH, and temperature. Lead adsorption by ferrous sulphide …
Published in International Journal of Chemical Engineering and Processing · Vol. 2, Issue 2, 2016 · pp. 33–41 Read article
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A Study of Thermodynamics of Ligand - Receptor Interaction in Chemical Sciences
Abstract: The formation and separation of definite non-covalent interactions between varieties of macromolecules play a crucial role in the function of biological systems. During the last few years, three main lines of research led to a dramatic improvement of our understanding of these important phenomena. First, combination of genetic engineering and X ray crystallography made available a simultaneous knowledge of the precise structure and affinity of series or related ligand-receptor systems …
Published in International journal of Thermodynamics and Chemical Kinetics · Vol. 3, Issue 2, 2017 · pp. 12–16 Read article
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Predictive Modelling of a Bioreactor for the Production of Ethanol Using Palmwine
Abstract: This research focuses on the feasibility of biochemical technology with yeast cells (Sacccharomycees cerevisiae) for continuous ethanol production from palm wine. This was carried out in a non-isothermal batch reactor at constant room temperature. 1.5L of palm wine solution was reacted with dry active baker’s yeast until reaction was completed. Biomass, ethanol and glucose concentration were sampled every two hours, and kinetic rate parameters for the fermentation calculated using concentration/time …
Published in International Journal of Chemical Synthesis and Chemical Reactions · Vol. 5, Issue 2, 2019 · pp. 1–8 Read article