Search
75 articles for “Reaction Mechanisms”
-
Indigo Carmine Oxidations in Aqueous and Micellar Media Using Specific Oxidants—A Review Article
Abstract: Abstract Indigo carmine is an anionic synthetic dye widely used in textile, food, and pharmaceutical industries. The discharge of this dye into water bodies poses severe environmental concerns due to its intense color, more stability, and resistance to biodegradation. Consequently, the oxidation and degradation of this dye through electron transfer reactions have been widely investigated. The present review focuses on studies related to oxidation of indigo carmine dye using various …
Published in International journal of Thermodynamics and Chemical Kinetics · Vol. 12, Issue 1, 2026 · pp. 44–56 Read article
-
Non-Equilibrium Entropy Pathways in Complex Fluids: A New Framework for Thermodynamic Irreversibility
Abstract: When a system is driven, sheared, stretched, heated, or pressurized under varying thermodynamic gradients and kept away from equilibrium, ultra-microscopic rearrangements begin to occur, indicating continuous energy dissipation. Along these energy pathways, the microstructures of complex fluids undergo multiple stages of reforming and rearrangement. In complex fluids composed of identical compounds (chemically identical species), these interactions play a supportive role and reduce the overall entropy of the system. However, when …
Published in International journal of Thermodynamics and Chemical Kinetics · Vol. 11, Issue 2, 2025 · pp. 1–7 Read article
-
Analytical Application of Radioactive Analysis
Abstract: A radioactive tracer, or radioactive label, is a chemical compound in which one or more atoms have been replaced by a radioisotope so by virtue of its radioactive decay it can be used to explore the mechanism of chemical reactions by tracing the path that the radioisotope follows from reactants to products. Keywords: radioactive tracer, chemical analysis, radioisotopes, atoms and molecules
Published in International Journal of Analytical and Applied Chemistry · Vol. 3, Issue 2, 2017 · pp. 32–35 Read article
-
KINETICS AND MECHANISM OF OXIDATION OF MIXTURE OF OXALIC ACID AND ADIPIC ACID BY CHROMIC ACID IN PRESENCE OF HYDROCHLORIC ACID
Abstract: The kinetics of oxidation of mixture of oxalic acid and adipic acid by chromic acid in presence of hydrochloric has been studied. The products are succinic acid and carbon dioxide. The rate of oxidation increases with the increase in the concentration of HCl acid. kinetics of oxidation of mixture of oxalic acid and adipic acid by chromic acid shows first order reaction at 270 c, order of the reaction is …
Published in International journal of Thermodynamics and Chemical Kinetics · Vol. 4, Issue 1, 2018 · pp. 23–27 Read article
-
Corrosion Protection of Rebar steel in Ocean Atmosphere
Abstract: Rebar is an important engineering metal. It is used in construction of housing, bridge and other infrastructures works. It is surround with concrete for strengthen building block components. The concentration of chloride ions in ocean atmosphere is higher so it produces hostile environment for rebar steel. The lots of porosities are available on the outer surface area of concrete so chloride ions enter inside by osmosis or diffusion process. It …
Published in International Journal of Energetic Materials · Vol. 8, Issue 1, 2022 · pp. 1–11 Read article
-
Study of the Effect of SLS Loading on the One-Pot Synthesis of Substituted Piperidines
Abstract: Piperidine derivatives represent a vital class of nitrogen-containing heterocycles with extensive pharmacological and industrial significance. Their synthesis has garnered considerable interest due to their presence in numerous bioactive molecules, including drugs with CNS activity, analgesic properties, and antimicrobial effects. Traditional multi-step synthetic pathways are often time-consuming and resource-intensive. To address this, one-pot multicomponent reactions (MCRs) have emerged as an efficient and eco-friendly alternative, allowing for the rapid construction of complex …
Published in International Journal of Green Chemistry · Vol. 12, Issue 1, 2026 · pp. 1–9 Read article
-
Corrosion Protection of Copper Metal by Nanocoating in Nitrogen dioxide Environment
Abstract: Nitrogen dioxide is an acidic gas. It absorbs moisture to produce nitric acid. It creates corrosive medium for copper metal. It forms corrosion cell on the surface of copper and accelerate corrosion reactions. The corrosion cell formation is written as: Cu|Cu2+||H+|H2 thus corrosion reactions start and copper is oxidized into Cu2+surface and it is oxidized into Cu2+ whereas H+ ion is reduced into H2. Nitric acid environment copper exhibits galvanic, …
Published in International journal of Thermodynamics and Chemical Kinetics · Vol. 8, Issue 1, 2022 · pp. 1–11 Read article
-
Synthesis of Bromobutyl Rubber: Effect of Reaction Temperature and Time on Bromobutyl Rubber Microstructure
Abstract: Butyl rubber is prepared by cationic polymerization process either by solution or slurry phase by randomly copolymerizing isobutylene with small amount of isoprene (1-3 mol %). It has good air impermeability and oxidative stability and thus finds extensive use in inner tube applications. The presence of unsaturation in the form of isoprene units in butyl rubber provides a means of enhancing useful properties of this important commodity elastomer by incorporation …
Published in International Journal of Composite Materials and Matrices · Vol. 9, Issue 1, 2023 · pp. 30–39 Read article
-
Studies on the Kinetics of Thermal Decomposition of Copper Oxalate Mixed With Silver Oxalate
Abstract: The coprecipitates, Ag2Cu(C2O4)nH2O of varying composition [Ag = (1 and 2)%], have been synthesized and were characterized by means of IR, XRD, and SEM. The decomposition of the prepared oxalates was monitored by differential scanning calorimetry (DSC) and thermogravimetry (TG). The DSC studies reveal that the decompositions of the mixed oxalates were all complex exothermic processes with resemblance to the exothermic reaction of copper oxalate and ranges from 540 to …
Published in International journal of Thermodynamics and Chemical Kinetics · Vol. 2, Issue 1, 2016 · pp. 1–11 Read article
-
Organic Compound 5-(4-methoxybenzyl)-N-phenyl-1,3,4-thiadiazol-2-amine and NiS filler used to Mitigation the Corrosion of Mild steel and in Marine Atmosphere
Abstract: The concentration of chloride ions is higher in marine atmosphere. The bulk amount of mild steel uses in sea weather for different works. This metal is very sensitive in chloride ions. It produces hostile environment for mild steel. Chloride ions develop corrosion cell on the surface of mild steel and it changes their external and internal morphology as well as physical, chemical and mechanical properties. Mild steel exhibits corrosion reaction …
Published in International Journal of Metallurgy and Alloys · Vol. 5, Issue 2, 2019 · pp. 56–64 Read article
-
AN OUTLINE OF KINETICS VERSUS THERMODYNAMICS CHEMISTRY
Abstract: Nearly all chemical reactions has a kinetic and a thermodynamic feature. The terms ‘kinetic’ and ‘thermodynamic’ though inter-related are two diverse aspects of a chemical reaction. This paper represents an outline of the underlying relationships between the two through application to chemical reactions and an example from natural processes. A required condition for thermodynamic control is reversibility or a mechanism allowing the equilibration between products. In this manner, the thermodynamically …
Published in International journal of Thermodynamics and Chemical Kinetics · Vol. 3, Issue 2, 2017 · pp. 17–20 Read article
-
Chemical Process of Diamonds and CVD Methods
Abstract: Many times, first-order kinetics can be seen in gas-phase decomposition events. However, it is now known that such reactions are actually governed by bimolecular processes. Bimolecular collisional activation to an energy sufficient for decomposition sets off the reaction. Gas-phase processes occurring in catalytic cycles are also to blame for the development of the ozone hole in the polar stratosphere in the spring, albeit heterogeneous mechanisms must also be taken into …
Published in International journal of Thermodynamics and Chemical Kinetics · Vol. 8, Issue 1, 2022 · pp. 12–17 Read article
-
A Comprehensive Review of Classical Thermodynamics:Principles, Laws, and Applications
Abstract: Classical thermodynamics, a fundamental branch of physics and engineering, provides a macroscopicframework for understanding energy, work, and heat interactions in physical systems. This reviewcomprehensively examines the principles, laws, and practical applications of classicalthermodynamics, emphasizing its enduring relevance in modern science and engineering. Beginningwith the foundational concepts of system, surroundings, state, and equilibrium, the study explores theformulation and significance of the four laws of thermodynamics. The Zeroth Law establishes the basisfor …
Published in International journal of Thermodynamics and Chemical Kinetics · Vol. 12, Issue 1, 2026 · pp. 19–26 Read article
-
Kinetics and Mechanism of Ruthenium(III) Catalysed Oxidation of L-Arginine by Periodate in Alkaline Medium
Abstract: The kinetics of the ruthenium(III) catalysed oxidation of L-arginine by periodate was studied spectrophotometrically in alkaline medium at 280 nm and at a temperature 35 ± 0.1°C. It was found that the reaction is first order with respect to [catalyst] and [periodate]. The reaction showed fractional order dependence on [substrate] and [alkali]. The oxidation product of the reaction was found to be aldehyde. The anionic species of arginine (Arg) is …
Published in International journal of Thermodynamics and Chemical Kinetics · Vol. 2, Issue 1, 2016 · pp. 12–20 Read article
-
Spectrophtometric Study of Catalysed Oxidation of Some Cyclic Alcohols by N-bromophthalimide
Abstract: The spectrophotometric kinetic investigation of cyclohexanol and cycloheptanol catalysed by Keggin type anion [PW12O40]3- with N-bromophthalimide have been carried out in 30% acetic acid medium in absence of mercuric(II) acetate and in presence of sulphuric acid. The observed kinetic data was used for the justification of Beer-Lambert law. The reactions follow a fractional-order with respect to cyclic alcohols, PTA catalyst and first-order with respect to oxidant NBP. The added H+ …
Published in International Journal of Chemical Synthesis and Chemical Reactions · Vol. 5, Issue 1, 2019 · pp. 44–50 Read article
-
Finite Element Analysis (FEA) for Nonlinear Behavior in Advanced Materials
Abstract: (FEA) in investigating the nonlinear behavior of advanced materials plays a pivotal role in optimizing the design and performance of modern structural systems. As innovative materials, such as nanocomposites, metamaterials, and shape-memory alloys gain prominence, conventional linear modeling methods become inadequate for accurately capturing the intricate and time-dependent responses exhibited by these materials under diverse loading conditions. This research delves into cutting-edge FEA techniques to simulate and analyze the nonlinear …
Published in International Journal of Structural Engineering and Analysis · Vol. 11, Issue 1, 2025 · pp. 21–26 Read article
-
Advanced Recent Synthesis and characterization of SnO2 NPs using Aristolochia bracteolata leaf Extract and multy Application
Abstract: The SnO2 nanoparticle was synthesised by sol-gel method and sonication technique. SnO2 nanoparticle using Aristolochia bracteolata leaf Extract. Aristolochia bracteolata is a shrup distributed in India, this family Aristolochiaceae, it is used in the medicine. The nanoparticle was characterized by HR-SEM with (EDX), (HR-TEM), XRD analysis, photoluminescence spectroscopy (PL) and UV-Vis DRS. This nanopartricles was photodegradation of Rhodamine B dye under the UV-light irradiation at 365 nm. The hydroxyl radical …
Published in International Journal of Green Chemistry · Vol. 4, Issue 2, 2018 · pp. 25–36 Read article
-
Study of Thermal Stresses on Cast Iron and Aluminum Alloy V8 Cylinder Blocks for A Four Stroke CI Engine Without any Application of Cooling Systems
Abstract: The purpose of this paper is to investigate the thermal stresses experienced by a V8 cylinder block of a four stroke CI engine at a specific point in time during the engine's operation. Two case studies were performed for the cylinder block with different materials. Aluminum A356 T6 and Iron Cast are the materials used in these case studies for the cylinder block. Pressures and temperatures were applied only to …
Published in International Journal of I.C. Engines and Gas Turbines · Vol. 7, Issue 2, 2021 · pp. 6–19 Read article
-
Catalytic Steam recycle of Bio-Oil Produces Hydrogen
Abstract: The "water-gas shift reaction" is a process that combines the vapour and carbon monoxide to produce carbon dioxide and more hydrogen.Steam reforming of actual bio-oil is a more realisticmethod for producing H2 despite substantial research on the heat reform of model compounds (such as ethanol). With a focus on the creation of catalysts for the procedure, this paper covers current developments in the steam reforming of actual bio-oil. Given its …
Published in International Journal of Renewable Energy and its Commercialization · Vol. 8, Issue 1, 2022 · pp. 25–29 Read article
-
Study of Recyclable Thermoset Polymers Using Dynamic Covalent Bonds
Abstract: Thermoset polymers are widely used in advanced engineering applications due to their excellent mechanical strength, thermal resistance, and chemical stability. However, their permanent three-dimensional cross-linked networks make them traditionally non-recyclable, contributing significantly to polymer waste and environmental challenges. In recent years, dynamic covalent chemistry (DCC) has emerged as a transformative approach for designing recyclable thermoset materials by incorporating reversible and exchangeable bonds within their structure. This project focuses on the …
Published in International Journal of Energetic Materials · Vol. 11, Issue 2, 2025 · pp. 1–10 Read article