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60 articles for “Metal Complexes”
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Review Paper on Mannich Bases for Heterocyclic Compound Synthesis
Abstract: Mannich bases are the Lewis bases which are β-amino carbonyl compounds synthesized as the endproducts of well known condensation reaction known as Mannich reaction. These are theaminoalkylation reactions involving the formation of carbon-carbon, carbon-Nitrogen, carbonsulphurbonds. Mannich bases of 2-furylmethylketone, catechol, 4-chlorophenol, derivative ofberberine, lawsone, anisaldehyde, benzaldehyde show diversity of biological activities. Mannichreaction is a carbon-carbon bond forming nucleophilic addition reaction and is a key step in synthesisof a widespread variety …
Published in International Journal of Chemical Synthesis and Chemical Reactions · Vol. 7, Issue 1, 2021 · pp. 39–50 Read article
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Survey on Semicarbazide and Thiosemicarbazide Derivatives
Abstract: This review insurances around semicarbazide and thiosemicarbazide with derivatives throughpresentation of their preparation methods, reactions like cyclization processes. Thiosemicarbazonesand semicarbazones are an important class of ligands for the synthesis of transition metal complexeswith applications in medicine and electrochemistry, also in organic chemistry fields., Tumor is amalignant in addition invasive development or cancer, particularly of epithelium derivation, whichinclines to recur after erasure also may metastasize to other places. It befalls due …
Published in International Journal of Chemical Synthesis and Chemical Reactions · Vol. 7, Issue 1, 2021 · pp. 51–57 Read article
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Sustainable Hydrogen Solutions: Beryllium-Based Complexes and Catalysts for Efficient Energy Storage and Production
Abstract: This study explores the potential of beryllium (Be) and transition metal (TM) complexes in hydrogen storage and production, focusing on the hybridization of atomic orbitals to form dihydrogen complexes within nanostructured materials. We analyze the binding energies and adsorption characteristics of H₂ molecules in Be-dihydrogen complexes and compare them with TM-dihydrogen complexes. The findings indicate that Be can effectively bind H₂ at room temperature, making it a promising candidate for …
Published in International Journal of Energetic Materials · Vol. 10, Issue 2, 2024 · pp. 1–5 Read article
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ISONIAZID STABILIZED TUNGSTEN TRICARBONYL COMPLEX: A NEW CO-RELEASING MOLECULE WITH ANTIBACTERIAL ACTIVITY
Abstract: Transition metal carbonyl complexes substituted with biologically active ligand can act as CO-releasing molecules which have beneficial roles including antimicrobial activity. Careful choices of ancillary ligand such as isoniazid help in eliminating issues of toxicity that may arise from drug substrates. Substitution reaction of tungsten hexacarbonyl with isoniazid in the presence of trimethylamine N-oxide under nitrogen atmosphere was carried out at ambient temperature for 72 hrs. The product was characterized …
Published in International Journal of Chemical Synthesis and Chemical Reactions · Vol. 5, Issue 1, 2019 · pp. 36–43 Read article
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Review on Electrolytic Process by Refining the Metals
Abstract: Electrolysis is a method of purifying impure metals. The crude metal that needs to be refined serves as the anode in an electrolytic cell while the metal that has been purified serves as the cathode. To ensure that the metal at the cathode is reduced extremely specifically, the electrode potential is chosen. Impurities are left behind in the electrolyte liquid as the metal is transferred from theunrefined metal of the …
Published in International Journal of Metallurgy and Alloys · Vol. 8, Issue 1, 2022 · pp. 5–9 Read article
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Thermodynamic study of Pr(III) complex in mixed solvent system at 303.15K
Abstract: A conductance study of the interaction between Pr(III) complex in mixes solvent system at 303.15K. The metal-ligand stability constant of the complex was determined by conductance measurements. The free energy change of the complex was investigated at 303.15K using thermodynamic relations, the negative values of free energy means that the complex formation process is spontaneously.Key word: metal –ligand stability constant, conductometry., thermodynamics relations
Published in International journal of Thermodynamics and Chemical Kinetics · Vol. 6, Issue 2, 2020 · pp. 16–19 Read article
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SYNTHESIS AND IR-SPECTROSCOPIC STUDY OF MIXED LIGAND COMPLEX COMPOUNDS OF COPPER (II) FORMAT WITH SOME AMIDES
Abstract: Complex compounds of metals with amides, having biological activity are widely used in agriculture. Complex compounds of copper with organic ligands are physiologically active, participating in the vital processes of living organisms; the formiats have bactericidal and fungicidal properties. For the first time, mixed ligand complex compounds of copper (II) formate with formamide, thiocarbamide, acetamide and carbamide in an aqueous solution were synthesized. Using the methods of IR spectroscopy and …
Published in International Journal of Chemical Synthesis and Chemical Reactions · Vol. 6, Issue 2, 2020 · pp. 31–38 Read article
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Preparation and Characterization of Mixed Ligand Complexes of Cobalt(II) and Ni(II) salt of Phthalimide with Some Oxamic Acids
Abstract: The mixed ligand complexes of oxamic acids with Co(II) and Ni(II) salt of phthalimide were prepared, where oxm= N-phenyl thio urea oxamic acid(NPTUOA),m-tolumide oxamic acid (m-TOA), N-pyrrazole oxamic acid & phth= Co(II) and Ni(II) salt of phthamlimide. These all mixed ligand complexes examined by their elemental analysis, melting points, UV-visible analysis, I.R studies, magnetic susceptibility measurements and thin layer chromatography. Elemental analysis of the complexes shows 1:2 (Metal:Ligand) stiochiometry for …
Published in International Journal of Chemical Synthesis and Chemical Reactions · Vol. 3, Issue 1, 2017 Read article
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Nanocoating and Electrospray Techniques Use to Mitigation Corrosion Sculptures
Abstract: The most sculptures of the world are created by the brass, bronze, iron, silver, gold and metalloid. They come in contact of corrosive pollutants to produce chemical, electrochemical and biochemical reactions and develop various form of corrosion like uniform corrosion, galvanic corrosion, pitting corrosion, stress corrosion and crevice corrosion. The corrosive gases CO2, NO2 and SO2 concentrations increase in atmosphere rapidly after industrialization. The major contributors of these gases are …
Published in International Journal of Metallurgy and Alloys · Vol. 8, Issue 2, 2022 · pp. 1–11 Read article
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Basic Principles and Techniques in Powder Metallurgy
Abstract: This study provides a brief overview of recent advances in powder metallurgy methods, and their applications as challenges encountered throughout the research. The primary goal of this paper is to showcase the different uses of modern powder metallurgy technology and to inspire visitors to learn more about these topics and produce more papers about it. Metallic injection moulding (MIM) is another term for advanced powder metallurgy. The technique could be …
Published in International Journal of Metallurgy and Alloys · Vol. 8, Issue 1, 2022 · pp. 1–4 Read article
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A Broad Review on the Impact of spring back/spring go During Bending Operation
Abstract: AbstractSpring back is the most important element impacting the perfection of sheet metal components because of the spring back properties of sheet metal, designing forming dies is particularly complex. This is a critical issue since spring back is a common forming issue with metal forming process using high-strength steel sheets. Once a stress is released, the material's elastic recovery forces the metal to spring back into shape. There are several …
Published in International Journal of Manufacturing and Materials Processing · Vol. 8, Issue 1, 2022 · pp. 14–19 Read article
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Metals from Plantation to Search Toxicity
Abstract: Ascent of sap by plant tissues absorbs chemical complexes for ingrowth. Trace elemental complexes have been as require by successive growth strategies as per standards. Therefore, heavy elements in soil compositions have adhered other than morphological, which have been either in excess or others under composed variations. Soil content ever has studied to be primary issue to assess the possibilities of polluting elemental containment. Examples are innumerable; however some of …
Published in International Journal of Plant Biotechnology · Vol. 6, Issue 1, 2020 · pp. 1–9 Read article
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Preparation and Characterization of Ce-Si-SBA-15 Modified With Iron
Abstract: Recently environmental concerns have driven the development of specialized catalysts to prevent polluting substances from being released into the environment. New technologies have improvised our understanding of catalytic functions as well as selectivity in order to save the energy and chemicals. Today, catalysis is the workhorse in the chemical industry with approximately >90% of the products produced in catalytic processes. In addition, life cannot exist without catalysis, as virtually all …
Published in International Journal of Chemical Synthesis and Chemical Reactions · Vol. 2, Issue 1, 2016 Read article
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Synthesis, Characterization and Biological Studies Using X-Beam Crystal Structures Which Utilizes (1) Cu Kα Data with Synchrotron Data
Abstract: The outcomes demonstrate that the complex responds as a bidentate ligand and is bound to the metal particle through the two oxygen iotas of the ligand (HL). The enactment energies, ΔE*, entropies ΔS*, enthalpies ΔH* and request of responses have been gotten from differential thermo-gravimetric (DTA) bends. In light of hindrance zone breadth estimations, the complex showed noteworthy antibacterial movement against both Staphylococcus aureus and Escherichia coli. It additionally displayed …
Published in International journal of Nanobiotechnology · Vol. 3, Issue 1, 2017 · pp. 1–5 Read article
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Quantum Dots in Oral Diagnostics and Theranostics:Promise and Preclinical Status
Abstract: Quantum dots in oral diagnostics and theranostics represent a rapidly evolving, largely preclinical strategy that couples highly sensitive optical imaging with targeted therapeutic delivery in the oral cavity. Their size-dependent emission, high photostability, and broad excitation spectra allow bright, multiplexed visualization of key molecular events in oral potentially malignant disorders and oral squamous cell carcinoma, while surface functionalization with antibodies, peptides, or small-molecule ligands enables selective binding to dysplastic and …
Published in International Journal of Applied Nanotechnology · Vol. 12, Issue 1, 2026 · pp. 20–30 Read article
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A Study on the Future of Industrial WastewaterTreatment Plant: Trends and Innovations
Abstract: Industrial wastewater treatment plants (IWWTPs) stand at the critical intersection of economic productivity and environmental sustainability. Unlike municipal sources, industrial effluent is characterized by extreme heterogeneity, containing highly variable concentrations of toxic heavy metals, recalcitrant organic compounds, suspended solids, and emerging contaminants. This complexity necessitates bespoke, multistage treatment trains, often combining physical, chemical, and advanced biological methods (e.g., membrane bioreactors, electrochemical oxidation, and anaerobic digestion). This analysis examines the contemporary …
Published in International Journal of Chemical Engineering and Processing · Vol. 11, Issue 2, 2025 · pp. 1–13 Read article
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An Overview on Metal Processing using Machine Learning
Abstract: Metalworking, which is an important part of modern industry, includes a wide range of steps, such as shaping and casting the metal, machining it, and riveting it. The industry has always relied on trial and error and other empirical methods, but machine learning (ML) is now causing a big change. It is expected that this change will lead to higher production, better product quality, and better use of resources. The …
Published in International Journal of Manufacturing and Materials Processing · Vol. 12, Issue 1, 2026 · pp. 43–53 Read article
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Synthesis, Structural Elucidation, and Antimicrobial Screening of a Cobalt (II) Coordination Compound Derived from a Thiophene-Containing Schiff Base
Abstract: Abstract An N, O-chelating azomethine Schiff base ligand (HL), chemically identified as 2-{[(thiophen-2-yl) methylidene] amino} benzoic acid, was synthesized by an equimolar condensation reaction between thiophene-2-carbaldehyde and anthranilic acid in absolute ethanol in the presence of a catalytic amount of acetic acid. The corresponding cobalt (II) complex, formulated as [Co(L)₂] · 2H₂O, was prepared by refluxing two equivalents of the ligand with one equivalent of cobalt (II) acetate tetrahydrate in …
Published in International Journal of Analytical and Applied Chemistry · Vol. 12, Issue 2, 2026 · pp. 1–7 Read article
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A Review of Recent Developments in Solid State-Based Metal Additive Manufacturing: Friction Stir Additive Technique
Abstract: In the age of machines, the whole industry needs light-weight and high strength for lighter devices, machines, etc. The core aerospace industry needs lighter materials for satellites and rockets. Friction Stir Additive Technology (FSAT)represents an innovative approach aimed at leveraging the principles of layered build (AM) layer by layer using solid state (FSW) friction stir welding technology. These represent a particular class of friction-based additive technology (FAT) and can easily …
Published in International Journal of Manufacturing and Materials Processing · Vol. 8, Issue 2, 2022 · pp. 17–25 Read article
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Noble metal nanoparticles for electrochemical oxidation and sensor of Glucose
Abstract: The electrochemical oxidation of glucose without enzyme is one of the aims that many researchers have been trying to achieve. The non-enzymatic glucose oxidation attains closer to practical applications. The electrochemical oxidation of glucose molecules involves complex processes of adsorption, electron transfer, and subsequent chemical rearrangement, which are combined with the surface reactions on the metal surfaces. The information about the direct oxidation of glucose on solid-state surfaces as well …
Published in International Journal of Nanomaterials and Nanostructures · Vol. 4, Issue 2, 2018 · pp. 1–5 Read article