All articles
112 articles
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Thermal Dynamics and Kinetic Modelling of Cryogenic Fuels in Aerospace and IndustrialApplications
Abstract: Cryogenic fuels are critical for high-speed aerospace and industrial applications, where efficient handling, storage, and usage are paramount for performance and safety. This study explores the thermal dynamics and kinetic modeling of cryogenic fuels, focusing on liquid handling systems and propellant technologies. Utilizing computational fluid dynamics (CFD) analysis, the research evaluates the behavior of cryogenic liquids within insulated vessels under extreme temperature conditions, identifying key parameters that influence thermal stability …
Published in International journal of Thermodynamics and Chemical Kinetics · Vol. 10, Issue 2, 2024 Read article
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Kinetic Modifications in Polymers under Cryogenic Stress: A Thermochemical Study
Abstract: This study explores the kinetic modifications in polymers subjected to cryogenic stress, focusing on the thermochemical behavior and structural changes that occur at low temperatures. Polymers, when exposed to cryogenic conditions, exhibit distinct molecular rearrangements, influencing their mechanical properties and thermal stability. The investigation involves characterizing these polymers using advanced spectroscopic and thermal analysis techniques to identify alterations in crystallinity, molecular weight distribution, and glass transition temperature. By examining the …
Published in International journal of Thermodynamics and Chemical Kinetics · Vol. 10, Issue 2, 2024 Read article
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Modeling the Biokinetic of Crude Oil Degradation inLoamy Soil Using the Citrus Sinensis of Flavedo Part
Abstract: The biokinetic parameters of crude oil degradation using Citrus sinensis of flavedo part was investigated in loamy soil environment. Mathematical models were developed for the purpose of determining the biokinetic parameters of the k1 (Total Petroleum Hydrocarbon), maximum specific rate of TPH remediation and dissociation constant of the TPH remediation on the effect of remediant dosage on the polluted loamy soil environment. The effect of the remediants were monitored for …
Published in International journal of Thermodynamics and Chemical Kinetics · Vol. 10, Issue 1, 2024 Read article
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Investigation on the Characteristics of Chromolaena Odorata (Awolowo leaf) in Petroleum Hydrocarbon Degradation in Loamy Soil Environment
Abstract: The application of Chromolaena odorata (Awolowo leaf), processed into powder form, was used as a biostimulant for petroleum hydrocarbon degradation and mitigation in a loamy soil environment. In this investigation, the physicochemical and microbial characteristics of the sample were determined, as presented in this research, including pH, electrical conductivity (EC), total nitrogen (T.N), total phosphorus (T.P), potassium (K), total organic carbon, and P. fluorescence. Corynebacterium sp., Arthrobacter, Bacillus, Acinetobacter iwoffi, …
Published in International journal of Thermodynamics and Chemical Kinetics · Vol. 10, Issue 1, 2024 · pp. 13–23 Read article
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Impact of Cryogenic Temperatures on the Mechanical and Thermal Properties of Polymers and Composites
Abstract: The development of lightweight, high-performance materials for use in cryogenic environments is crucial for advanced applications in aerospace, energy storage, and industrial sectors. This study explores the thermodynamic and mechanical behavior of fiber-reinforced polymers and composite materials under extremely low-temperature conditions. The cryogenic performance of these materials, including their thermal stress resistance and impact properties, was assessed with a focus on polymer fragility and the durability of composites at temperatures …
Published in International journal of Thermodynamics and Chemical Kinetics · Vol. 10, Issue 1, 2024 · pp. 7–12 Read article
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Kinetic Modeling of Biomass Pyrolysis for Renewable Energy Production.
Abstract: Biomass pyrolysis is a promising technology for renewable energy production, offering a sustainable alternative to fossil fuels. This process involves the thermal decomposition of organic materials in the absence of oxygen, resulting in the generation of bio-oil, syngas, and biochar. Kinetic modeling of biomass pyrolysis is essential for optimizing the process and enhancing the yield and quality of the products. This abstract presents a comprehensive review of kinetic models used …
Published in International journal of Thermodynamics and Chemical Kinetics · Vol. 10, Issue 1, 2024 · pp. 1–6 Read article
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Thermodynamic of Biomass Pyrolysis of RenewableEnergy Production
Abstract: Biomass pyrolysis is a pivotal thermochemical process for converting organic materials into valuable biofuels and chemicals, playing a critical role in the renewable energy landscape. This study explores the thermodynamic principles underlying biomass pyrolysis, emphasizing its potential for sustainable energy production. In this process, biomass is thermally broken down in the absence of oxygen, producing syngas, biochar, and bio-oil. Thermodynamic analysis provides insights into the energy requirements, reaction pathways, and …
Published in International journal of Thermodynamics and Chemical Kinetics · Vol. 10, Issue 1, 2024 Read article
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Exploring Thermodynamic Heterocyclic Compounds: A Comprehensive Analysis
Abstract: Heterocyclic compounds constitute a significant class of organic molecules with diverse applications in various fields including pharmaceuticals, materials science, and agrochemicals. Understanding their thermodynamic properties is crucial for elucidating their behavior in different environments and optimizing their applications. This comprehensive analysis delves into the thermodynamic aspects of heterocyclic compounds, encompassing their synthesis, structural characteristics, and energetics. The review begins by outlining the fundamental principles governing the thermodynamics of heterocyclic compounds, …
Published in International journal of Thermodynamics and Chemical Kinetics · Vol. 9, Issue 1, 2023 · pp. 40–46 Read article
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Hot and Cold Fluid: The Concepts of Split Range Control Model
Abstract: The MATLAB tools were used in the research for monitoring the potential of hot and cold fluid application and the integrity of split range control model as related to the effect of temperature. The temperature of the cold fluid was within the room temperature and the temperature of the hot fluid was at elevated temperature. The research showcases decrease in hot fluid with increase in cold fluid, which demonstrate the …
Published in International journal of Thermodynamics and Chemical Kinetics · Vol. 9, Issue 1, 2023 · pp. 28–39 Read article
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Laws of Thermodynamics Challenge Greenhouse-Gas and CLIMATE- change Hypotheses
Abstract: The greenhouse-gas hypothesis (GGH), i.e., CO2 is the cause of global warming by ~1K from ~1950-2023, is popularly believed to be established scientific truth. It is generally assumed that heat emissions from global fuel combustion are, by comparison, negligible. An application of the Hess-Gibbs 1st law of thermodynamics, however, shows that the enthalpy (H) output from yearly fossil fuel consumption is seven times greater than the H- increase of hypothetical …
Published in International journal of Thermodynamics and Chemical Kinetics · Vol. 9, Issue 1, 2023 · pp. 7–19 Read article
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Effect of Benzene Ring on Thermodynamic Parameters of Three Mono Azo Disperse Dyes on Nylon Fabric (Sudan I, Ii And Iv)
Abstract: In this study, three dyes - Sudan I, Sudan II, and Sudan IV - were tested for their performance on nylon fabric at different temperatures (50oC, 70oC, and 100oC). The thermodynamic properties of the dyes, including the partition coefficient (K), percentage dye exhaustion (%E), standard enthalpy change, standard affinity change, and standard change in entropy, were examined. The findings showed that the values of the thermodynamic parameters for the dyes …
Published in International journal of Thermodynamics and Chemical Kinetics · Vol. 9, Issue 1, 2023 · pp. 01–06 Read article
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Thermodynamic Optimization of Renewable Energy Processes
Abstract: In the pursuit of sustainable energy solutions, the thermodynamic optimization of renewable energy processes plays a crucial role in enhancing efficiency and reducing environmental impact. This paper explores the principles and methodologies involved in optimizing various renewable energy systems, including solar, wind, biomass, and geothermal energy. By leveraging the fundamentals of thermodynamics, the study examines key parameters and performance indicators to identify optimal operating conditions and design configurations. The analysis …
Published in International journal of Thermodynamics and Chemical Kinetics · Vol. 9, Issue 2, 2023 · pp. 31–37 Read article
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Novel Approaches to Thermodynamic Optimization in Industrial Processes
Abstract: Thermodynamic optimization in industrial processes stands as a pivotal pursuit in enhancing efficiency, sustainability, and economic viability. Traditional methodologies have primarily focused on established principles, yet the escalating demands for resource conservation and emissions reduction necessitate innovative strategies. This abstract presents a compendium of novel approaches aimed at revolutionizing thermodynamic optimization in industrial settings. Firstly, the incorporation of advanced machine learning algorithms unveils unprecedented opportunities for predictive modeling and real-time …
Published in International journal of Thermodynamics and Chemical Kinetics · Vol. 9, Issue 2, 2023 · pp. 20–25 Read article
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Synthesis and Mechanistic Interpretation of Hydrolytic Dephosphorylation of Monoamidate of 2,4-dichloro aniline phosphate in Acid Media
Abstract: Synthesis of mono 2.4-dichloroanniline phosphate was carried out using POCl3 as phosphorylating reagent and the kinetic study of monoamidate of 2,4-dichloroaniline phosphate was conducted in an acidic medium ranging from 0.01 to 7.0 mol dm-3at a temperature of 50°C. A notable feature of the acid log rate profile was the presence of a rate maximum at 4.0 mol dm-3. The decrease in rate beyond 4.0 mol dm-3 can be explained …
Published in International journal of Thermodynamics and Chemical Kinetics · Vol. 9, Issue 2, 2023 · pp. 26–30 Read article
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Effect of Temperature on Particle Size Mixed Ratio on Petroleum Hydrocarbon Treatment in Packed Bed Unit using Adsorbent
Abstract: The significance of temperature on the potential characteristics of the adsorbent performance in treatment of polluted water medium was monitored by using both room and sun dried bioadsorbent. The research furthermore showcases the effect of particle size of the bioadsorbent in the treatment process and obtained result revealed that the particle size is a contributing factor to the efficiency and the potential in which the rate of Total Petroleum Hydrocarbon …
Published in International journal of Thermodynamics and Chemical Kinetics · Vol. 9, Issue 2, 2023 · pp. 1–12 Read article
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A Comprehensive Characterization of Zinc Chloride: Unveiling its Role as a Hygroscopic Preservative and Drying Agent through Elemental, Structural, and Morphological Analysis
Abstract: This study presents a detailed investigation of Zinc Chloride( )) utilizing the following different analytical techniques, X-ray diffraction(XRD), Electron Dispersive Spectroscope (EDS), Transmission Electron Microscope (TEM), Scanning Electron Microscope (SEM). Zinc Chloride was synthesized using the hydrothermal method. The elemental, structural, morphological, and optical properties of Zinc Chloride ( )) were thoroughly analyzed. The hygroscopic nature and properties of Zinc Chloride upon exposition to air was revealed and its weight/mass …
Published in International journal of Thermodynamics and Chemical Kinetics · Vol. 9, Issue 2, 2023 · pp. 13–19 Read article
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Thermodynamic and Kinetic Characterization of Aluminum Corrosion and Inhibition Adsorption of Vernonia Amygdalina Fruit Extract IN 0.5N H2SO4
Abstract: Anti-corrosive efficacy of ethanolic extract of Vernonia amygdalina fruit extract on corrosion of aluminum in 0.5N H2SO4 acidic solution was explored by mass loss measurement at rise in temperature between 303-343 K for 24 hours immersion period. The I.E. (η%) has been noticed prominently high (62.92%) at concentration 0.45% at 303 K. An inhibitor adsorption on the surface aluminum have been found to be best fitted Langmuir adsorption isotherm. It …
Published in International journal of Thermodynamics and Chemical Kinetics · Vol. 9, Issue 1, 2023 · pp. 20–27 Read article
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Investigation of Mild Steel Corrosion by Clay Soil Environment
Abstract: This research work was carried out to observe the microbiologically induced corrosion in relation to mild steel of clay soil environments. We analyzed the physicochemical parameters and ascertained their biological features and impacts in the soil environment. In course of this research work, clay soil samples were collected in exactly four different locations at 100 m to 200 m and mixed together to form a single sample (sample D). The …
Published in International journal of Thermodynamics and Chemical Kinetics · Vol. 8, Issue 2, 2022 · pp. 54–63 Read article
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Simulation of Heat Generated on Crude Oil Degradation upon the Effect of Temperature in Bacteria Growth Kinetics in a Bioreactor
Abstract: Model was established to simulate the heat generated by bacteria with the interaction of substrate (crude oil) degradation in a bioreactor upon the influence of temperature. The model was predicted by simulating the characteristics of bacteria interaction with substrate at temperature of 15oC, 30oC, 45oC, 60oC, 75oC, 90oC, 105oC and 120oC and heat generated is within the range of -1.0 to 7.1kcal/hr for bacteria in fresh water medium whereas for …
Published in International journal of Thermodynamics and Chemical Kinetics · Vol. 8, Issue 2, 2022 · pp. 39–54 Read article
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High-rate Deformation of Condensed Matter Followed by Self-Organization on the Mesoscale
Abstract: The purpose of the paper is to demonstrate the advantages of the developed self-consistent non-local approach to the description of processes in condensed matter far from local thermodynamic equilibrium and new opportunities for understanding and practical use of such phenomena as self-organization, multi-scale energy exchange and turbulence. This interdisciplinary approach, based on rigorous results obtained in non-equilibrium statistical mechanics with the use of feedback control laws, offers a universal mathematical …
Published in International journal of Thermodynamics and Chemical Kinetics · Vol. 8, Issue 2, 2022 · pp. 13–38 Read article