International Journal of Chemical Synthesis and Chemical Reactions
Volume 2, Issue 1 (2016)
Published
Table of contents
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Synthesis and Characterization of Cadmium exchanged Sodalite
Abstract: Cadmium derivative of chloro sodalite, has been synthesized at low temperature by hydrothermal method. The sodalite is characterized by IR, X-ray powder diffraction and SEM. The Cd derivative was obtained by facile exchange of cadmium for sodium in chloro sodalite using a solution of cadmium nitrate in Teflon autoclaves at 100oC. The IR spectra of parent gallo silicate chloro sodalite and cadmium exchanged chloro sodalites shows three kinds of IR …
Published in International Journal of Chemical Synthesis and Chemical Reactions · Vol. 2, Issue 1, 2016 Read article
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Elucidation of Synthetic Mechanism Involved in the Conversion of Zwitterionic Clonixin to Carboxamide Side-Product
Abstract: N-(3-Chloro-2-methylphenyl)-2-oxo-1,2-dihydropyridine-3-carboxamide is obtained as a by-product during the synthesis and crystallization of Clonixin (2-(3-chloro-2-methylanilino)nicotinic acid) and its polymorphs, respectively. This conversion was unexpected and it changed the usual investigation path way enabling the formation of neutral and zwitterionic polymorphs in our study on Clonixin in contrary to studies of 2-(p-tolylamino) nicotinic acid investigation. The same conversion is checked in the other synthesized analogs such as 2-(phenylamino)nicotinic acid (PNA), 2-(methyl(phenyl)amino)nicotinic acid …
Published in International Journal of Chemical Synthesis and Chemical Reactions · Vol. 2, Issue 1, 2016 Read article
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Preparation and Characterization of Ce-Si-SBA-15 Modified With Iron
Abstract: Recently environmental concerns have driven the development of specialized catalysts to prevent polluting substances from being released into the environment. New technologies have improvised our understanding of catalytic functions as well as selectivity in order to save the energy and chemicals. Today, catalysis is the workhorse in the chemical industry with approximately >90% of the products produced in catalytic processes. In addition, life cannot exist without catalysis, as virtually all …
Published in International Journal of Chemical Synthesis and Chemical Reactions · Vol. 2, Issue 1, 2016 Read article
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Ultrasonic Study of Binary Liquid Mixtures of Triethyl Amine With Primary Alcohols at 303.15 K
Abstract: Most of the physical properties change whenever there is a change in the composition and structure of the liquid mixture. Then non-linear dependence of the physical–chemical properties with composition has been attributed to the size, shape, and polarity of the molecules. Ultrasonic velocity is one such property which is very important for the study of molecular interactions in solution. It gives information about the extent of interaction and some other …
Published in International Journal of Chemical Synthesis and Chemical Reactions · Vol. 2, Issue 1, 2016 Read article
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Studies on Zirconium(IV) Telluroiodate: A New Heteropolyacid Based Inorganic Ion Exchange Material
Abstract: Zirconium (IV) telluroiodate has been synthesized as a new inorganic cation exchanger by adding a mixture of aqueous solution of 0.1 M potassium iodate and 0.1 M sodium tellurite to aqueous solution of 0.1 M zirconium (IV) oxychloride under varying mixing ratios at pH 1. Its ion exchange capacity for Na+ was found to be 1.85 meqg1 of dry exchanger. The material has been characterized on the basis of chemical …
Published in International Journal of Chemical Synthesis and Chemical Reactions · Vol. 2, Issue 1, 2016 Read article