1 publication

• Published Subscription 29 Jul 2016

  The decomposition of tris-(oxalato)-manganate (III) complex ion as the reaction suitable for the laboratory practice on chemical kinetics

  By Pavel Anatolyevich Nikolaychuk, Mariya Mikhaylovna Vayner

  Abstract: The complex ion [Mn(C2O4)3]3- is very photosensitive and rapidly decomposes at the daylight even at ambient temperatures. Although the mechanism of this reaction is complicated, its kinetic equation obeys the pseudo-first order. In addition, the tris-(oxalate)-manganate ion has a low thermal stability, and the reaction of its decomposition is highly affected by temperature. This makes this reaction very suitable for demonstrating the laws of chemical kinetics to the students – …

  Published in International journal of Thermodynamics and Chemical Kinetics · Vol. 2, Issue 2, 2016 · pp. 1–10 Read article →