2 publications

• Published Subscription 29 Jun 2020

  Synthesis of Different types of Heterocycles are used by Claisen rearrangement reaction

  By M. N Sivakumar, M. Sasikumar, N. Venkatesan, P. Hariharan

  Abstract: The Claisen rearrangement is a powerful tool for carbon-carbon bond-forming reaction which was discovered by Rainer Ludwig Claisen. The discovery of the Claisen rearrangement nearly a century ago accessible a potentially useful synthetic tool to the organic chemist. Utility of this rearrangement over the decades has been realized and the reaction has drawn the consideration of numerous research groups, which has been showed in the number of publication on the …

  Published in International Journal of Chemical Synthesis and Chemical Reactions · Vol. 6, Issue 1, 2020 · pp. 44–48 Read article →

• Published Subscription 13 Feb 2020

  Different type of catalysts used in the Baylis-Hillman reaction

  By M. N Sivakumar, M. Sasikumar, M. Sivakumar

  Abstract: The Baylis-Hillman reaction in the present-day version is an atom-economic carbon-carbon bond-forming reaction between the α-position of the activated alkenes and carbon electrophiles under the influence of a catalyst or catalytic system offering diverse classes of densely functionalized molecules. If the substrate contains both the activated alkene and electrophile components in appropriate positions, there is the possibility of developing an intramolecular version of this reaction leading to the synthesis of …

  Published in International Journal of Chemical Synthesis and Chemical Reactions · Vol. 5, Issue 2, 2019 · pp. 30–37 Read article →