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Kinetics and Mechanism of Ruthenium(III) Catalysed Oxidation of L-Arginine by Periodate in Alkaline MediumBy Garapati Sridevi, Nowduri Annapurna, Parvataneni Vani
Abstract: The kinetics of the ruthenium(III) catalysed oxidation of L-arginine by periodate was studied spectrophotometrically in alkaline medium at 280 nm and at a temperature 35 ± 0.1°C. It was found that the reaction is first order with respect to [catalyst] and [periodate]. The reaction showed fractional order dependence on [substrate] and [alkali]. The oxidation product of the reaction was found to be aldehyde. The anionic species of arginine (Arg) is …
Published in International journal of Thermodynamics and Chemical Kinetics · Vol. 2, Issue 1, 2016 · pp. 12–20 Read article →